Insights into the semiclassical Wigner treatment of bimolecular collisions

被引：4

作者：

Bonnet, L. ^{[1
]}

机构：

[1] Univ Bordeaux, CNRS, ISM, UMR 5255, F-33405 Talence, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 2013年 / 139卷 / 11期

关键词：

PHOTODISSOCIATION DYNAMICS; MOLECULAR-COLLISIONS; CHEMICAL-REACTIONS; S-MATRIX; SCATTERING; APPROXIMATION;

D O I：

10.1063/1.4819954

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The semiclassical Wigner treatment of bimolecular collisions, proposed by Lee and Scully on a partly intuitive basis [J. Chem. Phys. 73, 2238 (1980)], is derived here from first principles. The derivation combines Heller's ideas [J. Chem. Phys. 62, 1544 (1975); 65, 1289 (1976); 75, 186 (1981)], the backward picture of molecular collisions [L. Bonnet, J. Chem. Phys. 133, 174108 (2010)] and the microreversibility principle. (C) 2013 AIP Publishing LLC.

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页数：11

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