Crystal structure and electrochemical behavior of an unusual nitrosyl-Ru complex obtained by a reaction of Ru2(Me COO)4 Cl with 2-pyridinecarboxylic acid

被引:5
作者
Yukawa, Y
Igarashi, S
Horiike, H
Nagao, H
Howell, FS
Mukaida, M
机构
[1] Niigata Univ, Fac Sci, Dept Environm Sci, Niigata 9502181, Japan
[2] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[3] Sophia Univ, Dept Chem, Fac Sci & Engn, Chiyoda Ku, Tokyo 1028554, Japan
关键词
D O I
10.1246/cl.1999.733
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure and the electrochemical behavior of a Ru-complex, which was obtained from a reaction of [Ru-2(MeCOO)(4)Cl] with 2-pyridinecarboxylic acid and NO2-, were investigated: the complex consists of nitrosyl, 2-pyridinecarboxylato, and acetato ligands. The cyclic voltammogram showed no redox wave in the region of the potential window, unlike common Ru(NO)-complexes.
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页码:733 / 734
页数:2
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