Mild, Rapid, and Inexpensive Microwave-Assisted Synthesis of Allylic and Propargylic Esters

被引：3
|
作者：
Gill, Monica A. [1 ]
Manthorpe, Jeffrey M. [1 ]
机构：
[1] Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada
来源：
SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 10期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
Allylic esters; esterification; microwave-assisted synthesis; mixed anhydride; propargylic esters; CLAISEN REARRANGEMENT; CARBOXYLIC ESTERS; DIHYDROXYLATION; REAGENTS;
D O I：
10.1080/00397911.2011.640970
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of allylic and propargylic esters were rapidly prepared via microwave heating of their corresponding mixed anhydride derived from pivaloyl chloride. The reaction conditions were modified to account for the sterics of the alcohol and the electronics of the carboxylic acid. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
引用
收藏
页码：1460 / 1468
页数：9
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