Isoxazolone-based single crystals with large second harmonic generation effect

被引：19

作者：

Zhang, Xinyuan ^{[1
,2
]}

Jiang, Xingxing ^{[1
,2
]}

Li, Yin ^{[1
]}

Lin, Zheshuai ^{[1
]}

Zhang, Guochun ^{[1
]}

Wu, Yicheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 38期

基金：

中国国家自然科学基金;

关键词：

NONLINEAR-OPTICAL PROPERTIES; CONFIGURATIONALLY LOCKED POLYENE; TERAHERTZ-WAVE GENERATION; STILBAZOLIUM-SALT; DIPOLE-MOMENT; ELECTRON-GAS; AB-INITIO; GROWTH; DERIVATIVES; CHROMOPHORES;

D O I：

10.1039/c5ce01006c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two nonlinear optical (NLO) crystals based on the 3-phenyl-5-isoxazolone moiety, (Z)-4-(4-(dimethylamino) benzylidene)-3-phenylisoxazol-5(4H)-one (C18H16N2O2, DLS) and (Z)-4-(4-methoxybenzylidene)-3-phenylisoxazol-5(4H)-one (C17H13NO3, MLS), have been successfully grown by a slow evaporation method. The powder second-harmonic generation intensities of DLS and MLS are strong, about 2.8 and 1.5 times that of OH1, respectively. Such a large SHG effect is further elucidated by structure analyses and theoretical calculations. The optical and thermal properties of DLS and MLS have been characterized by UV-vis absorption spectroscopy, IR spectroscopy, thermal gravimetric analysis and differential scanning calorimetry.

引用

页码：7316 / 7322

页数：7

共 50 条

[21] Second harmonic generation in Na3Gd2(BO3)3 crystals [J].

Zhou, W. W. ;

Zhuang, R. Z. ;

Zhao, W. ;

Wang, G. F. ;

Zhang, L. Z. ;

Ma, J. G. ;

Bao, X. ;

Wang, F. W. ;

Chen, Y. H. .

CRYSTAL RESEARCH AND TECHNOLOGY, 2011, 46 (09) :926-930

[22] Effect of Li and NH4 doping on the crystal perfection, second harmonic generation efficiency and laser damage threshold of potassium pentaborate crystals [J].

Vigneshwaran, A. N. ;

Kalainathan, S. ;

Raja, C. Ramachandra .

OPTICS AND LASER TECHNOLOGY, 2018, 100 :153-156

[23] Enhancing the optical properties of sodium 4-nitrophenolate dehydrate single crystals: role of second and third harmonic generation efficiencies [J].

Vijayakumar, K. ;

Palani, P. ;

Thiyagarajan, M. ;

Kotteswaran, S. ;

Vetrivel, S. ;

Saleem, H. ;

Vinitha, G. ;

Purushothaman, P. .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2023, 34 (19)

[24] Large Magnetization-Induced Second Harmonic Generation in an Enantiopure Chiral Magnet [J].

Train, Cyrille ;

Nuida, Tomohiro ;

Gheorghe, Ruxandra ;

Gruselle, Michel ;

Ohkoshi, Shin-ichi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) :16838-16843

[25] Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials [J].

Cheng, Xiyue ;

Li, ZhenHua ;

Wu, Xin-Tao ;

Hong, Maochun ;

Whangbo, Myung-Hwan ;

Deng, Shuiquan .

ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (08) :9434-9439

[26] Significant second-harmonic generation and bulk photovoltaic effect in trigonal selenium and tellurium chains [J].

Cheng, Meijuan ;

Shi, Xiaohong ;

Wu, Shunqing ;

Zhu, Zi-Zhong .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (11) :6823-6831

[27] Effect of oxygen pressure on second harmonic generation in zinc oxide thin films deposited by PLD [J].

Li Shuhong ;

Liu Yunlong ;

Wang Qingru ;

Shi Qiang ;

He Xiaoxiao ;

Gao Xuexi ;

Zhang Dong ;

Wang Wenjun .

OPTICS COMMUNICATIONS, 2015, 356 :546-550

[28] Effect of L-alanine, Mn(II) and glycine dopants on the structural, crystalline perfection, second harmonic generation (SHG), dielectric and mechanical properties of BTCA single crystals [J].

Ganesh, V. ;

Rao, T. Bhaskar ;

Rao, K. Kishan ;

Bhagavannarayana, G. ;

Shkir, Mohd .

MATERIALS CHEMISTRY AND PHYSICS, 2012, 137 (01) :276-281

[29] Effect of composition and temperature on the second harmonic generation in silver phosphate glasses [J].

Konidakis, I. ;

Psilodimitrakopoulos, S. ;

Kosma, K. ;

Lemonis, A. ;

Stratakis, E. .

OPTICAL MATERIALS, 2018, 75 :796-801

[30] High second harmonic generation in ferroelectric nematic liquid crystals by doping with optimally oriented chromophores [J].

Ortega, Josu ;

Folcia, Cesar Luis ;

Sierra, Teresa .

LIQUID CRYSTALS, 2025,

← 1 2 3 4 5 →