Synthesis and comparative performance study of crystalline and partially amorphous nano-sized SnS2 as anode materials for lithium-ion batteries

被引:14
作者
Glibo, Albina [1 ,2 ]
Eshraghi, Nicolas [1 ]
Mautner, Andreas [3 ]
Jahn, Marcus [1 ]
Flandorfer, Hans [2 ]
Cupid, Damian M. [1 ]
机构
[1] AIT Austrian Inst Technol GmbH, Ctr Low Emiss Transport, Giefinggasse 2, A-1210 Vienna, Austria
[2] Univ Vienna, Dept Inorgan Chem Funct Mat, Josef Holaubek Pl 2, A-1090 Vienna, Austria
[3] Univ Vienna, Dept Mat Chem, Wahringer Str 42, A-1090 Vienna, Austria
关键词
SnS2; Hydrothermal method; Precipitation reaction; Lithium-ion battery; Anode; TIN; NANOPARTICLES; NANOSHEETS; ELECTRODES; LITHIATION;
D O I
10.1016/j.electacta.2022.140869
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A facile, time effective, and energy efficient precipitation reaction method was developed to synthesize amorphous/nano crystalline SnS2 using SnCl(4)middot5H(2)O and thioacetamide (C2H5NS) as Sn and S sources, respectively. As a comparison, nano-crystalline SnS2 was also synthesized via the already established hydrothermal method using the same Sn- and S precursors. The crystal structure, chemical composition, and morphology of both obtained products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. The electrochemical performance properties of the as-synthesized SnS2 samples were investigated using galvanostatic cycling with potential limitation, cyclic voltammetry, electrochemical impedance spectroscopy and electrochemical in-situ dilatometry. The results show that SnS2 prepared via the precipitation reaction method electrochemically outperforms that from the hydrothermal method. This is due to the formation of thicker Li2S layers on the particle surfaces, which drastically limits the volume expansion of the Sn particles during the alloying reaction with lithium.
引用
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页数:13
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