Kinetic analysis of the atom transfer radical polymerization of butyl acrylate mediated by Cu(I)Br/N,N,N′,N′,N"-pentamethyldiethylenetriamine

被引：0

作者：

Reyes, M

Yu, X

Shipp, DA ^{[1
]}

机构：

[1] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA

[2] Clarkson Univ, Ctr Adv Mat Proc, Potsdam, NY 13699 USA

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2001年 / 202卷 / 17期

关键词：

atom transfer radical polymerization (ATRP); catalysis; kinetics (polym.);

D O I：

10.1002/1521-3935(20011101)202:17<3268::AID-MACP3268>3.0.CO;2-H

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics atom transfer radical polymerization (ATRP) of n-butyl acrylate, using the Cu(I)Br/ N,N,N′,N′,N″-pentamethyldiethylenetriamine catalytic system and methyl-2-bromopropionate as initiator, is studied. The orders of the initiator, activator and deactivator are estimated for two systems - one close to bulk conditions (5 vol.-% toluene added), and another with 10 vol.-% N,N-dimethylformamide added. The former system gave non-integer orders for initiator and activator, while the latter gave orders of unity for both of these reactants. The second system gave a non-linear response for the deactivator. © Wiley-VCH Verlag GmbH, 2001.

引用

页码：3268 / 3272

页数：5

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