Extraction of Pd(II), Rh(III) and Ru(III) from HNO3 aqueous solution to betainium bis(trifluoromethanesulfonyl) imide ionic liquid

被引：63

作者：

Sasaki, Kotoe ^{[1
]}

Takao, Koichiro ^{[2
]}

Suzuki, Tomoya ^{[2
]}

Mori, Takahiro ^{[2
]}

Arai, Tsuyoshi ^{[1
]}

Ikeda, Yasuhisa ^{[2
]}

机构：

[1] Shibaura Inst Technol, Dept Mat Sci, Koto Ku, Tokyo 1358548, Japan

[2] Tokyo Inst Technol, Res Lab Nucl Reactors, Meguro Ku, Tokyo 1528550, Japan

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 15期

基金：

日本学术振兴会;

关键词：

NITRIC-ACID; COMPLEXES; CHEMISTRY;

D O I：

10.1039/c4dt00091a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Extraction efficiencies of Pd(II), Rh(III), and Ru(III) from HNO3(aq) to [Hbet][Tf2N] were demonstrated, i.e., Pd(II) is the most extractable, Rh(III) is medium extractable, and Ru(III) is the least extractable. The extraction seems to proceed through coordination of betaine to the metal ions and the cation exchange of the formed complex with H+.

引用

页码：5648 / 5651

页数：4