Design of atomically dispersed catalytic sites for photocatalytic CO2 reduction

被引：71

作者：

Xia, Tong ^{[1
,2
]}

Long, Ran ^{[1
,2
]}

Gao, Chao ^{[1
,2
]}

Xiong, Yujie ^{[1
,2
]}

机构：

[1] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, iChEM Collaborat Innovat Ctr Chem Energy Mat, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Sch Chem & Mat Sci, Hefei 230026, Anhui, Peoples R China

来源：

NANOSCALE | 2019年 / 11卷 / 23期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; PHOTOREDUCTION; EFFICIENT; TIO2; FABRICATION; CONVERSION; SYSTEM; WATER; CU;

D O I：

10.1039/c9nr03616d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalytic conversion of CO2 into carbonaceous chemical fuels and building blocks is an intriguing strategy for solving fossil energy crisis and reducing CO2 emission. Recently, development of atomically dispersed catalytic sites for photocatalytic CO2 reduction has sparked tremendous interest as their coordinatively unsaturated states, tunable electronic structures and well-defined active sites provide versatile knobs for tuning CO2 conversion. While this Minireview mainly highlights recent key developments in this important research field and elucidates the common fundamentals behind various materials systems, it also provides insights into the future development and emphasizes opportunities and challenges.

引用

收藏

页码：11064 / 11070

页数：7

相关论文

共 40 条

[11] ACTIVATION OF THE C-C BOND PROVIDES A MOLECULAR-BASIS FOR STRUCTURE SENSITIVITY IN METAL CATALYSIS [J].

KIRLIN, PS ;

GATES, BC .

NATURE, 1987, 325 (6099) :38-40

[12] Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals [J].

Kuehnel, Moritz F. ;

Orchard, Katherine L. ;

Dalle, Kristian E. ;

Reisner, Erwin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (21) :7217-7223

[13] Device Fabrication for Water Oxidation, Hydrogen Generation, and CO2 Reduction via Molecular Engineering [J].

Li, Fusheng ;

Yang, Hao ;

Li, Wenlong ;

Sun, Licheng .

JOULE, 2018, 2 (01) :36-60

[14] Static Regulation and Dynamic Evolution of Single-Atom Catalysts in Thermal Catalytic Reactions [J].

Li, Hongliang ;

Wang, Menglin ;

Luo, Laihao ;

Zeng, Jie .

ADVANCED SCIENCE, 2019, 6 (03)

[15] Porphyrin-sensitized solar cells [J].

Li, Lu-Lin ;

Diau, Eric Wei-Guang .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (01) :291-304

[16] Ethylenediamine-functionalized CdS/tetra(4-carboxyphenyl)porphyrin iron (III) chloride hybrid system for enhanced CO2 photoreduction [J].

Li, Pan ;

Hou, Chunchao ;

Zhang, Xuehua ;

Chen, Yong ;

He, Tao .

APPLIED SURFACE SCIENCE, 2018, 459 :292-299

[17] Visible-light-driven CO2 photoreduction over ZnxCd1-xS solid solution coupling with tetra(4-carboxyphenyl)porphyrin iron(iii) chloride [J].

Li, Pan ;

Zhang, Xuehua ;

Hou, Chunchao ;

Lin, Lin ;

Chen, Yong ;

He, Tao .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (25) :16985-16991

[18] Metal-Organic-Framework-Based Catalysts for Photoreduction of CO2 [J].

Li, Rui ;

Zhang, Wang ;

Zhou, Kun .

ADVANCED MATERIALS, 2018, 30 (35)

[19] Design and fabrication of semiconductor photocatalyst for photocatalytic reduction of CO2 to solar fuel [J].

Li, Xin ;

Wen, Jiuqing ;

Low, Jingxiang ;

Fang, Yueping ;

Yu, Jiaguo .

SCIENCE CHINA-MATERIALS, 2014, 57 (01) :70-100

[20] Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion [J].

Liang, Zibin ;

Qu, Chong ;

Xia, Dingguo ;

Zou, Ruqiang ;

Xu, Qiang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (31) :9604-9633

← 1 2 3 4 →