Multiphase Reaction Kinetics of Epoxidation of Polyisobutene

被引：0

作者：

Li, Mei ^{[1
]}

Xiao, Guomin ^{[1
]}

Chen, Zhiming ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 15期

关键词：

Epoxidation; Polyisobutene; Peracetic acid; Kinetics; Model; AQUEOUS HYDROGEN-PEROXIDE; IN-SITU; METHYL-ESTERS; SOYBEAN OIL; ACETIC-ACID;

D O I：

10.14233/ajchem.2013.14802

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of epoxidation of polyisobutene by peracetic acid generated in situ from hydrogen peroxide and acetic acid in the presence of solid acid WO3/ZrO2 were studied. The effect of several reaction parameters such as stirring speed, acetic acid-to-double bond molar ratio, temperature and content of catalyst were examined. Dynamic parameters were estimated using nonlinear regression method from the experimental data. A multiphase kinetic model of the epoxidation reaction was developed. There was good agreement between experimental and predicted data and simulation was performed to validate the model.

引用

页码：8493 / 8497

页数：5

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