Multiphase Reaction Kinetics of Epoxidation of Polyisobutene

被引：0
作者：
Li, Mei [1 ]
Xiao, Guomin [1 ]
Chen, Zhiming [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 15期
关键词：
Epoxidation; Polyisobutene; Peracetic acid; Kinetics; Model; AQUEOUS HYDROGEN-PEROXIDE; IN-SITU; METHYL-ESTERS; SOYBEAN OIL; ACETIC-ACID;
D O I：
10.14233/ajchem.2013.14802
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of epoxidation of polyisobutene by peracetic acid generated in situ from hydrogen peroxide and acetic acid in the presence of solid acid WO3/ZrO2 were studied. The effect of several reaction parameters such as stirring speed, acetic acid-to-double bond molar ratio, temperature and content of catalyst were examined. Dynamic parameters were estimated using nonlinear regression method from the experimental data. A multiphase kinetic model of the epoxidation reaction was developed. There was good agreement between experimental and predicted data and simulation was performed to validate the model.
引用
收藏
页码：8493 / 8497
页数：5
相关论文
共 18 条
  • [1] Bai X., 2010, Chinese Patent, Patent No. [101649168-A, 101649168]
  • [2] High yield epoxidation of fatty acid methyl esters with performic acid generated in situ
    Campanella, Alejandrina
    Fontanini, Carina
    Baltanas, Miguel A.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2008, 144 (03) : 466 - 475
  • [3] Chen Z., 2010, Chinese Patent, Patent No. [101781534-A, 101781534]
  • [4] ACETIC-ACID AS AN OXYGEN CARRIER BETWEEN 2 PHASES FOR EPOXIDATION OF OLEIC-ACID
    CHOU, TC
    CHANG, JY
    [J]. CHEMICAL ENGINEERING COMMUNICATIONS, 1986, 41 (1-6) : 253 - 266
  • [5] Davion B, 2010, POLYMER, V51, P5323, DOI [10.1016/j.polymer.2010.09.015, 10.1016/j.Polymer.2010.09.015]
  • [6] Epoxidation of cottonseed oil by catalysed by liquid aqueous hydrogen peroxide inorganic acids
    Dinda, Srikanta
    Patwardhan, Anand V.
    Goud, Valbhav V.
    Pradhan, Narayan C.
    [J]. BIORESOURCE TECHNOLOGY, 2008, 99 (09) : 3737 - 3744
  • [7] KINETIC-STUDIES OF EPOXIDATION AND OXIRANE CLEAVAGE OF PALM OLEIN METHYL-ESTERS
    GAN, LH
    GOH, SH
    OOI, KS
    [J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (04) : 347 - 351
  • [8] Kinetics of epoxidation of jatropha oil with peroxyacetic and peroxyformic acid catalysed by acidic ion exchange resin
    Goud, Vaibhav V.
    Patwardhan, Anand V.
    Dinda, Srikanta
    Pradhan, Narayan C.
    [J]. CHEMICAL ENGINEERING SCIENCE, 2007, 62 (15) : 4065 - 4076
  • [9] Hua H., 2009, Chinese Patent, Patent No. [101580610-A, 101580610]
  • [10] Kinetic study of cyclooctene epoxidation with aqueous hydrogen peroxide over silica-supported calixarene-Ta(V)
    Morlanes, Natalia
    Notestein, Justin M.
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 387 (1-2) : 45 - 54
12