meso-(5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradec-4,11-diene) copper(II) perchlorate; an unexpected preparation and structure determination

被引：1

作者：

Curtis, Neil F. ^{[1
]}

Wikaira, Jan ^{[2
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington 6140, New Zealand

[2] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

INORGANICA CHIMICA ACTA | 2013年 / 396卷

关键词：

Copper(II); Crystal structure; Tetraazamacrocycle; Isomerism; CRYSTAL-STRUCTURE; DICHLOROPLATINUM(II) COMPLEX; NICKEL(II); 5,5,7-TRIMETHYL-1,4-DIAZACYCLOHEPTANE; COORDINATION; DERIVATIVES; KINETICS;

D O I：

10.1016/j.ica.2012.11.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of (4,6,6-trimethyl-3,7-diaza-non-3-en-1,9-diamine)copper(II) perchlorate in water by NaBH4, followed by air oxidation, formed (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotertradec-4,11-diene) copper(II) perchlorate, for which the structure was determined, showing the meso-configuration of the square-planar coordinated copper(II) cation. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：14 / 16

页数：3

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