Fourier transform spectroscopy of the A(2)Sigma(+)-X-2 Pi(i) transition of AgO

被引：16
|
作者：
OBrien, LC
Wall, SJ
Sieber, MK
机构：
[1] Department of Chemistry, S. Illinois Univ. at Edwardsville, Edwardsville
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1997年 / 183卷 / 01期
关键词：
D O I：
10.1006/jmsp.1996.7253
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The A(2) Sigma(+)-X-2 Pi(i) near-infrared electronic transition of AgO was observed for the first time. The spectrum was recorded with the high resolution Fourier transform spectrometer associated with the McMath-Pierce Solar Telescope at Kitt Peak. The excited AgO molecules were produced in a low pressure silver hollow cathode sputter source. Constants for the A(2) Sigma(+) state of (AgO)-Ag-107 and (AgO)-Ag-109 and improved X-2 Pi(i) constants for (AgO)-Ag-107 and (AgO)-Ag-109 are presented. These two states are not a unique perturber pair and they do not follow the pure precession model. (C) 1997 Academic Press.
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页码：57 / 60
页数：4
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