High proton conductivity in an unprecedented anionic metalloring organic framework (MROF) containing novel metalloring clusters with the largest diameter

被引：46

作者：

Han, Yun-Hu ^{[1
,3
]}

Ye, Yingxiang ^{[2
]}

Tian, Chongbin ^{[1
]}

Zhang, Zhangjing ^{[2
]}

Du, Shao-Wu ^{[1
]}

Xiang, Shengchang ^{[2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350007, Peoples R China

[3] Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 48期

基金：

中国国家自然科学基金;

关键词：

SUPERPROTONIC CONDUCTIVITY; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; METAL; MOFS; ACID; SEPARATION; ACETYLENE; MIXTURES; SUBZERO;

D O I：

10.1039/c6ta07939c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An attractive anionic metalloring organic framework (MROF-1) containing unprecedented sextuply interlocked nanocages made up of original metalloring clusters with the largest diameter of ca. 21 angstrom shows a high proton conductivity up to 1.72 x 10(-2) S cm(-1) at 70 degrees C and 97% RH, owing to plenty of counter cations (Me2NH2)(+) located in the 1D channels.

引用

页码：18742 / 18746

页数：5

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