Preparation and Characterization of a Water-Soluble Conjugated Polymer-Iron(III) Chloride Complex

被引:4
|
作者
Gal, Yeong-Soon [1 ]
Jin, Sung-Ho [2 ]
Park, Jong-Wook [3 ,4 ]
Lim, Kwon Taek [5 ]
机构
[1] Kyungil Univ, Polymer Chem Lab, Coll Engn, Gyongsan 712701, Gyeongsangbuk D, South Korea
[2] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea
[3] Catholic Univ Korea, Dept Chem, Puchon 420743, South Korea
[4] Catholic Univ Korea, Ctr Nanotech Res, Puchon 420743, South Korea
[5] Pukyong Natl Univ, Div Image & Informat Engn, Pusan 608739, South Korea
基金
新加坡国家研究基金会;
关键词
Polyacetylene; 2-ethynylpyridine; poly(2-ethynyl-N-pentylpyridinium iodide); iron(III) chloride; electro-optical; cyclovoltammogram; IONIC POLYACETYLENES; ORGANIC POLYMERS; POLYMERIZATION; CYCLOPOLYMERIZATION; TRANSISTORS; BROMIDE);
D O I
10.1080/15421406.2012.690973
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A water-soluble ionic polyacetylene, poly(2-ethynyl-N-pentylpyridinium iodide) [PEPPI] was prepared by the uncatalyzed polymerization of 2-ethynylpyridine by using 1-iodopentane in high yield. PEPPI-iron(III) chloride complex was prepared by the reaction of PEPPI and iron(III) chloride in DMF and its properties were characterized. The electrical conductivity of PEPPI-iron(III) chloride complex was 4.3 x 10(-4) S/cm. The photoluminescence (PL) spectra of PEPPI-iron(III) chloride complex showed that the photoluminescence peak is located at 578 nm, corresponding to a photon energy of 2.15 eV. The cyclic voltammograms of PEPPI-iron(III) chloride complex exhibited irreversible electrochemical behaviors between the doped and undoped peaks. It was found that the kinetics of the redox process of polymer is controlled by the reactant diffusion process.
引用
收藏
页码:1 / 7
页数:7
相关论文
共 50 条
  • [1] Preparation and characterization of a highly water-soluble pendant fullerene polymer
    Sun, YP
    Liu, B
    Moton, DK
    CHEMICAL COMMUNICATIONS, 1996, (24) : 2699 - 2700
  • [2] Preparation and Properties of Water-soluble Conjugated Polyelectrolyte
    包祥俊
    HONG Ruibin
    HU Jianhua
    ZHONG Yiping
    刘平
    DENG Wenji
    Journal of Wuhan University of Technology(Materials Science), 2014, (04) : 854 - 857
  • [3] Preparation and properties of water-soluble conjugated polyelectrolyte
    Xiangjun Bao
    Ruibin Hong
    Jianhua Hu
    Yiping Zhong
    Ping Liu
    Wenji Deng
    Journal of Wuhan University of Technology-Mater. Sci. Ed., 2014, 29 : 854 - 857
  • [4] Preparation and Properties of Water-soluble Conjugated Polyelectrolyte
    Bao Xiangjun
    Hong Ruibin
    Hu Jianhua
    Zhong Yiping
    Liu Ping
    Deng Wenji
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2014, 29 (04): : 854 - 857
  • [5] Preparation of a water-soluble fluorescent polymer
    Gao, HF
    Wang, CC
    Yang, WL
    Fu, SK
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2004, A41 (04): : 357 - 371
  • [6] Spectral Properties of Water-Soluble Conjugated Polymer PFP/DNA/Porphyrin Complex
    Long Saran
    Wan Yan
    Xia Andong
    ACTA CHIMICA SINICA, 2015, 73 (07) : 723 - 728
  • [7] Synthesis and Characterization of a Water-Soluble Conjugated Polymer from the Uncatalyzed Polymerization of Ethynylpyridine
    Gal, Yeong-Soon
    Jin, Sung-Ho
    MACROMOLECULAR SYMPOSIA, 2013, 328 (01) : 20 - 24
  • [8] Preparation and characterization of water-soluble polymer supported palladium (II) complexes
    Wang, YP
    Zhang, HT
    Xiao, YN
    Wang, RM
    Chang, Y
    PROGRESS OF FINE CHEMISTRY AND FUNCTIONAL POLYMERS, 1998, : 229 - 230
  • [9] Preparation and characterization of water-soluble iron-sulfur cluster nanoparticles
    Peng Shu-Ge
    Zhang Xing-Tang
    Zhang Yu-Qing
    Huang Ya-Bin
    Du Zu-Liang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (01) : 169 - 172
  • [10] Recent Advances of the Water-Soluble Conjugated Polymer Brushes
    Lu Xiaomei
    Li Jie
    Hu Wenbo
    Deng Weixing
    Fan Quli
    Huang Wei
    PROGRESS IN CHEMISTRY, 2016, 28 (04) : 528 - 540