Electron ballistic characteristic optimization in individual MWCNT by oxygen plasma treatment

被引:1
作者
Hu, Chia-Te [1 ]
Wu, Jyh-Ming [1 ]
Yeh, Jien-Wei [1 ]
Shih, Han C. [1 ,2 ]
机构
[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan
[2] Chinese Culture Univ, Inst Mat Sci & Nanotechnol, Taipei 11114, Taiwan
关键词
CARBON NANOTUBES; ELECTROCATALYTIC ACTIVITY; REDUCTION; NANOPARTICLES; CATALYSTS; JUNCTIONS;
D O I
10.1039/c6ra21424j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Surface treatment and bonding oxygen species represent a practical method for strongly enhancing the ballistic characteristic of carbon nanotubes (CNTs) because the electrical properties strongly depend on the surface states. In this work, oxygen plasma was introduced onto the CNTs to remove the remaining defects, leading to a 44.8% improvement in the graphite-like sp2 bonding, which represents the graphite level of the CNTs. Moreover, oxygen species were bonded onto each individual CNT, as seen from the AES analysis. The conductive characteristics, such as resistivity, electron concentration, and electron mobility, for individual treated CNTs were optimized significantly under 20 s oxygen plasma treatment, giving values of 1.23 x 10(2) mu Omega cm, 6.36 x 10(18) cm(-3), and 8002.23 cm(2) V-1 s(-1), respectively. Furthermore, we demonstrated an experimental approach to grow aligned CNTs by substrate clamping configurations without a bias voltage or porous substrate, which simplifies the complexity of procedure preparation and enhances the opportunity for extracting individually treated CNTs to investigate their specific conductive characteristics.
引用
收藏
页码:107977 / 107983
页数:7
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