Revisiting the reaction of hydroxyl radicals with vicinal diols in water

被引：12

作者：

Jiang, Dong ^{[1
]}

Barata-Vallejo, Sebastian ^{[2
]}

Golding, Bernard T. ^{[1
]}

Ferreri, Carla ^{[2
]}

Chatgilialoglu, Chryssostomos ^{[2
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] CNR, ISOF, I-40129 Bologna, Italy

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 05期

关键词：

AQUEOUS-SOLUTION; REARRANGEMENTS; ANTIOXIDANTS; MECHANISMS; GLYCOL;

D O I：

10.1039/c1ob06538f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbonyl products of the reactions of hydroxyl radicals with three vicinal diols (ethane-1,2-diol, propane-1,2-diol and butane-2,3-diol) have been identified and quantified. Hydroxyl radicals were produced by gamma-radiolysis of N2O-saturated aqueous solutions. The reactions result in the formation of alkoxyl radicals (similar to 15%) followed by beta-fragmentation, and alpha-hydroxyl alkyl radicals that undergo H2O elimination. The latter process is part of a radical chain reaction at higher diol concentrations.

引用

页码：1102 / 1107

页数：6

共 50 条

[21] Reaction of ethylene with hydroxyl radicals: A theoretical study
Senosiain, Juan P.
Klippenstein, Stephen J.
Miller, James A.
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (21): : 6960 - 6970
[22] Predicting the reaction rate constants of micropollutants with hydroxyl radicals in water using QSPR modeling
Jin, Xiaohui
Peldszus, Sigrid
Huck, Peter M.
CHEMOSPHERE, 2015, 138 : 1 - 9
[23] Oxidation of thiram fungicide by hydroxyl radicals in water: A theoretical study on reaction mechanism and kinetics
Truong, Dinh Hieu
Ngo, Thi Chinh
Nguyen, Thi Le Anh
Nguyen, Thanh Tung
Taamalli, Sonia
El Bakali, Abderrahman
Louis, Florent
Dao, Duy Quang
VIETNAM JOURNAL OF CHEMISTRY, 2024, 62 (04) : 547 - 555
[24] CONCERNING THE PHOSPHORYLATION OF VICINAL DIOLS
YU, KL
KO, KY
FRASERREID, B
SYNTHETIC COMMUNICATIONS, 1988, 18 (05) : 465 - 468
[25] Formation of hydroxyl radicals from the reaction of water and oxygen over basic metal oxides
Hewett, KB
Anderson, LC
Rosynek, MP
Lunsford, JH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 6992 - 6997
[26] Vicinal effect on chlorination of diols
Nogueira, Diogo
Oliveira, Ricardo R.
Rocha, Alexandre B.
CHEMICAL PHYSICS, 2024, 585
[27] A SHOCK-TUBE STUDY OF THE REACTION OF METHYL RADICALS WITH HYDROXYL RADICALS
BOTT, JF
COHEN, N
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1991, 23 (11) : 1017 - 1033
[28] THE ACETALIZATION OF GLYOXAL BY VICINAL DIOLS
SANGSARI, FH
CHASTRETTE, F
CHASTRETTE, M
BLANC, A
MATTIODA, G
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1990, 109 (01): : 15 - 20
[29] Measurement of Hydroxyl Radicals in Radiolized Water Systems
Ouyang, Z.
Strack, G.
Sajo, E.
Ngwa, W.
MEDICAL PHYSICS, 2016, 43 (06) : 3619 - 3620
[30] PHOTOLYSIS OF WATER VAPOR + REACTIONS OF HYDROXYL RADICALS
UNG, AYM
BACK, RA
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1964, 42 (04): : 753 - &

← 1 2 3 4 5 →