Asymmetric total synthesis of (+)-monocerin

被引：13
作者：
Fang, Bowen [1 ]
Xie, Xingang [1 ]
Li, Huilin [1 ]
Jing, Peng [1 ]
Gu, Jixiang [1 ]
She, Xuegong [1 ,2 ]
机构：
[1] Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 47期
关键词：
Asymmetric synthesis; (+)-Monocerin; cis-Fused furobenzopyranones; METABOLIC PRODUCTS; MONOCERIN; CYCLIZATION; ANTIFUNGAL; CONCISE; ETHERS; ACIDS;
D O I：
10.1016/j.tetlet.2013.09.055
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A concise asymmetric total synthesis of (+)-monocerin has been accomplished. The cis-fused furobenzopyranone of monocerin was efficiently constructed via a Lewis acid-mediated stereoselective cyclization of 1,2,4-triols intermediate. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6349 / 6351
页数：3
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