Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization

被引：4
作者：
Mejia, Aurora [1 ]
Rodriguez, Laurent [1 ,2 ]
Schmitt, Charlene [1 ]
Andreu, Nathalie [1 ]
Favero, Cedrick [2 ]
Braun, Olivier [2 ]
Dupuis, Guillaume [2 ,3 ]
Deniau, Elise [1 ]
Reynaud, Stephanie [1 ]
Grassl, Bruno [1 ]
机构：
[1] UPPA, Inst Sci Analyt & Physicochim Environm & Mat IPRE, CNRS, UMR 5254,E2S, F-64000 Pau, France
[2] SNF SAS, ZAC Milieux, F-42163 Andrezieux, France
[3] Poweltec, ZAC RUEIL 2000,3 Rue Paul Heroult, F-92500 Rueil Malmaison, France
来源：
ACS OMEGA | 2019年 / 4卷 / 06期
关键词：
TRANSFER RADICAL POLYMERIZATION; POLY(2-ACRYLAMIDO-2-METHYLPROPANESULFONATE) POLYMERS; UNPERTURBED DIMENSIONS; CHAIN CHARACTERISTICS; POLYELECTROLYTES; STYRENE; POLYACRYLAMIDES; ACRYLAMIDE; XANTHATES; KINETICS;
D O I：
10.1021/acsomega.9b00975
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 X 10(6) g mol(-1). The products have been characterized in terms of molecular mass and viscosimetric properties.
引用
收藏
页码：11119 / 11125
页数：7
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