Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization

被引：5

作者：

Mejia, Aurora ^{[1
]}

Rodriguez, Laurent ^{[1
,2
]}

Schmitt, Charlene ^{[1
]}

Andreu, Nathalie ^{[1
]}

Favero, Cedrick ^{[2
]}

Braun, Olivier ^{[2
]}

Dupuis, Guillaume ^{[2
,3
]}

Deniau, Elise ^{[1
]}

Reynaud, Stephanie ^{[1
]}

Grassl, Bruno ^{[1
]}

机构：

[1] UPPA, Inst Sci Analyt & Physicochim Environm & Mat IPRE, CNRS, UMR 5254,E2S, F-64000 Pau, France

[2] SNF SAS, ZAC Milieux, F-42163 Andrezieux, France

[3] Poweltec, ZAC RUEIL 2000,3 Rue Paul Heroult, F-92500 Rueil Malmaison, France

来源：

ACS OMEGA | 2019年 / 4卷 / 06期

关键词：

TRANSFER RADICAL POLYMERIZATION; POLY(2-ACRYLAMIDO-2-METHYLPROPANESULFONATE) POLYMERS; UNPERTURBED DIMENSIONS; CHAIN CHARACTERISTICS; POLYELECTROLYTES; STYRENE; POLYACRYLAMIDES; ACRYLAMIDE; XANTHATES; KINETICS;

D O I：

10.1021/acsomega.9b00975

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 X 10(6) g mol(-1). The products have been characterized in terms of molecular mass and viscosimetric properties.

引用

页码：11119 / 11125

页数：7

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