Crystal structure of [Pt3S2(P(CH2OH)3)6](PF6)(OH)•H2O

被引：7

作者：

Anyushin, A. V. ^{[1
,2
]}

Sokolov, M. N. ^{[1
,2
]}

Virovets, A. V. ^{[1
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 03期

关键词：

platinum complexes; sulfide clusters; water-soluble complexes; crystal structure; hydrogen bonds; PT2S2; CORE; COMPLEXES; PALLADIUM(II); LIGANDS; CLUSTER;

D O I：

10.1134/S002247661303027X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Pt3S2(P(CH2OH)(3))(6)](PF6)(OH)center dot H2O (1) is obtained by a reaction of [Pt3S2(P(CH2OH)(3))(6)]Cl-2 with NH4PF6. The crystal structure of 1 was determined by a single crystal X-ray diffraction analysis (space group R{ie638-1}c, a = 12.0042(2) , c = 52.6879(11) , V = 6575.2(2), Z = 6, C18H57F6O20P7Pt3S2, d (x) = 2.385 g/cm(3), T = 150 K, R (1) = 0.044 for 2123 F (0) > 4 delta(F) until 2 theta(max) = 63A degrees). The cations contain a {Pt-3(mu(3)-S)(2)}(2+) core with nonbonding PtaEuro broken vertical bar Pt distances of 3.1536(6) . The Pt atoms are in a square planar environment; the Pt-S and Pt-P bond lengths are 2.3586(16) and 2.260(2) respectively.

引用

页码：638 / 641

页数：4

共 18 条

[1] Synthesis, crystal structure, aqueous speciation, and kinetics of substitution reactions in a water-soluble Mo3S4 cluster bearing hydroxymethyl diphosphine ligands [J].

Algarra, Andres G. ;

Basallote, Manuel G. ;

Fernandez-Trujillo, M. Jesus ;

Guillamon, Eva ;

Llusar, Rosa ;

Segarra, M. Dolores ;

Vicent, Cristian .

INORGANIC CHEMISTRY, 2007, 46 (18) :7668-7677

[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[3]

[Anonymous], SHELXTL PROGRAMS STR

[4]

[Anonymous], 1990, SADABAS PROGRAM EMPI

[5] Multifaceted reactions of P(CH2OH)3 with rhenium(V) precursors.: Synthesis, characterization, and X-ray structural studies of trans,trans,trans-[ReO2{P(CH2OH)3}2(py)2]Cl, trans,cis,cis-[ReO2{P(CH2OH)3}2(py)2]Cl, and novel alkoxide [Re(O)(μ-O)-(P{CH2OH}3)(μ-η2-P{CH2OH}2CH2O)]4 [J].

Berning, DE ;

Katti, KV ;

Barbour, LJ ;

Volkert, WA .

INORGANIC CHEMISTRY, 1998, 37 (02) :334-339

[6] CRYSTAL AND MOLECULAR-STRUCTURE AND P-31 AND PT-195 NMR-SPECTROSCOPY OF [PT3S2(PME2PH)6][BET4]2 - A TRINUCLEAR COMPLEX CONTAINING TRIPLY-BRIDGING SULFIDE LIGANDS [J].

BUSHNELL, GW ;

DIXON, KR ;

ONO, R ;

PIDCOCK, A .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (04) :696-702

[7] Extending knowledge on the nucleophilicity of the {Pt2S2} core:: Ph2PCH2CH2PPh2 as an alternative terminal ligand in [L2Pt(μ-S)2PtL2] metalloligands [J].

Capdevila, M ;

Carrasco, Y ;

Clegg, W ;

Coxall, RA ;

González-Duarte, P ;

Lledós, A ;

Ramírez, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17) :3103-3113

[8] RHODIUM(I), RHODIUM(III), PALLADIUM(II), AND PLATINUM(II) COMPLEXES CONTAINING LIGANDS OF TYPE PRNQ3-N(N=0,1, OR 2 R = ME, ET, BUT, OR PH Q = CH2OCOME OR CH2OH) [J].

CHATT, J ;

LEIGH, GJ ;

SLADE, RM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (19) :2021-2028

[9]

Chin CH, 1996, J ORGANOMET CHEM, V509, P101

[10] Selective two-phase-hydrogenation of sorbic acid with novel water soluble ruthenium complexes [J].

Driessen-Holscher, B ;

Heinen, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 570 (01) :141-146

← 1 2 →