Quantum cutting downconversion by cooperative energy transfer from Ce3+ to Yb3+ in borate glasses

被引:164
作者
Chen, Daqin [1 ]
Wang, Yuansheng [1 ]
Yu, Yunlong [1 ]
Huang, Ping [1 ]
Weng, Fangyi [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
D O I
10.1063/1.3040005
中图分类号
O59 [应用物理学];
学科分类号
摘要
Quantum cutting downconversion (DC) involving the emission of two near-infrared (NIR) photons for each ultraviolet (UV) photon absorbed is realized in the Ce3+/Yb3+ codoped borated glasses. Upon excitation of Ce3+ ion with an UV photon at 330 nm, Yb3+ ions emit two NIR photons at 976 nm through an efficient excitation of Ce3+: 5d and subsequent cooperative energy transfer (ET) from Ce3+:5d to Yb3+:F-2(5/2). The maximum ET efficiency and the corresponding DC quantum efficiency were estimated to be 74% and 174%, respectively. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.3040005]
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页数:3
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