Self-Assembly of a Supramolecular, Three-Dimensional, Spoked, Bicycle-like Wheel

被引：80

作者：

Lu, Xiaocun ^{[1
]}

Li, Xiaopeng ^{[2
]}

Cao, Yan ^{[1
]}

Schultz, Anthony ^{[1
]}

Wang, Jin-Liang ^{[1
,3
]}

Moorefield, Charles N. ^{[1
]}

Wesdemiotis, Chrys ^{[1
]}

Cheng, Stephen Z. D. ^{[1
]}

Newkome, George R. ^{[1
]}

机构：

[1] Univ Akron, Dept Polymer Sci, Dept Chem, Akron, OH 44325 USA

[2] Texas State Univ San Marcos, Dept Chem & Biochem, San Marcos, TX 78666 USA

[3] Beijing Inst Technol, Coll Chem, Beijing 100081, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 30期

基金：

美国国家科学基金会;

关键词：

coordination modes; N ligands; self-assembly; supramolecular chemistry; zinc; CRYSTAL-STRUCTURE; SHAPE-PERSISTENT; COMPLEXES; COORDINATION; NANOPRISMS; STRATEGIES; ARRAYS; ROUTE;

D O I：

10.1002/anie.201302362

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Where there′s a wheel, there′s a way: The terpyridine-based title system has been synthesized through a facile self-assembly process. Two tris(terpyridine) ligands possessing angles of either 120°or 60°between adjacent tpy units were mixed with a stoichiometric amount of Zn2+ (2:6:12) to generate the desired coordination-driven bicycle-like wheel (90 % yield). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7728 / 7731

页数：4

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