The Solubility of Hydrocarbon Gases in Glassy Polymers: Fractal Modeling

被引：2

作者：

Kozlov, Georgii V. ^{[1
]}

Cruz-Morales, Jorge A. ^{[2
]}

Vargas, Joel ^{[2
]}

Tlenkopatchev, Mikhail A. ^{[2
]}

机构：

[1] Kabardino Balkarian State Univ, Nalchik 360004, Russia

[2] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico

来源：

INTERNATIONAL JOURNAL OF POLYMER SCIENCE | 2013年 / 2013卷

关键词：

FREE-VOLUME; TRANSPORT; ANNIHILATION;

D O I：

10.1155/2013/529021

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This work describes the fractal modeling of the solubility of n-alkanes, n-alkenes, methylacetylene, allene, ethylacetylene, and butadiene hydrocarbon gases in glassy poly(vinyltrimethylsilane) (PVTMS). The proposed equation represents satisfactorily the solubility coefficients of the hydrocarbon gases in glassy PVTMS as a function of the fractal dimension of the polymer and the effective diameter of a gas penetrant molecule. It is found that the calculated solubility coefficients have a good correlation with the experimental data. The proposed model can predict the solubility of hydrocarbon gases in glassy polymers.

引用

页数：4

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