Synthesis and structure of the first heterodinuclear bis(borylene) complexes

被引:9
作者
Braunschweig, Holger [1 ]
Ye, Qing [1 ]
Damme, Alexander [1 ]
Radacki, Krzysztof [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
基金
欧洲研究理事会;
关键词
TERMINAL BORYLENE COMPLEXES; REACTION CHEMISTRY; THERMAL CONDITIONS; LIGANDS; BORON; MONONUCLEAR; GENERATION; RHODIUM; BF; CO;
D O I
10.1039/c3cc43877e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a facile synthesis of the first heterodinuclear bis(borylene) complex by reaction of an iron bis(borylene) complex with [Pt(PCy3)(2)], and its fully-reversible CO uptake and liberation reaction.
引用
收藏
页码:7593 / 7595
页数:3
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