Polymer-Supported N-Hydroxyphthalimide as Catalyst for Toluene and p-Methoxytoluene Aerobic Oxidation

被引：26

作者：

Kasperczyk, Kornela ^{[1
]}

Orlinska, Beata ^{[1
]}

Witek, Ewa ^{[2
]}

Latka, Piotr ^{[2
]}

Zawadiak, Jan ^{[1
]}

Proniewicz, Leonard ^{[2
]}

机构：

[1] Silesian Tech Univ, Dept Chem Organ Technol & Petrochem, PL-44100 Gliwice, Poland

[2] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

CATALYSIS LETTERS | 2015年 / 145卷 / 10期

关键词：

N-Hydroxyphthalimide; Polymer-supported catalysts; Oxidation; Toluene; p-Methoxytoluene; METAL-ORGANIC FRAMEWORK; MOLECULAR-OXYGEN; SOLVENT; BENZALDEHYDES; AUTOXIDATION; EFFICIENT; PRESSURE; COMPLEX; PHASE;

D O I：

10.1007/s10562-015-1578-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present study, N-hydroxyphthalimide (NHPI) was successfully immobilized on (aminomethyl) polystyrene and (chloromethyl) polystyrene via amide or ester bonds. The obtained polymer-supported NHPIs have demonstrated catalytic activity for the aerobic oxidation of toluene and p-methoxytoluene. The oxidations were performed using cobalt(II) salts as co-catalysts, in acetic acid as solvent or in more environmentally acceptable solvent-free system. The possibility of recovery and recycling of the obtained polymer-supported NHPIs was reported.

引用

页码：1856 / 1867

页数：12

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