Self-assembly of well-defined ferrocene triblock copolymers and their template synthesis of ordered iron oxide nanoparticles

被引:42
作者
Hardy, Christopher G. [1 ]
Ren, Lixia [2 ]
Ma, Shuguo [3 ]
Tang, Chuanbing [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[3] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA
基金
美国国家科学基金会;
关键词
NANOPOROUS THIN-FILMS; BLOCK-COPOLYMERS; ARRAYS; LITHOGRAPHY; ARRANGEMENT; MICELLES; POLYMERS; GRAPHOEPITAXY; NANOCRYSTALS; DEVICES;
D O I
10.1039/c2cc36756d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Well-defined ferrocene-containing triblock copolymers were synthesized by atom transfer radical polymerization and self-assembled into highly ordered hexagonal arrays of cylinders via solvent annealing. The thin films were further used as a template and converted into highly ordered iron oxide nanoparticles (alpha-Fe2O3) by UV/ozonolysis and thermal pyrolysis.
引用
收藏
页码:4373 / 4375
页数:3
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