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Self-assembly of well-defined ferrocene triblock copolymers and their template synthesis of ordered iron oxide nanoparticles
被引:42
|作者:
Hardy, Christopher G.
[1
]
Ren, Lixia
[2
]
Ma, Shuguo
[3
]
Tang, Chuanbing
[1
]
机构:
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[3] Univ S Carolina, Dept Chem Engn, Columbia, SC 29208 USA
基金:
美国国家科学基金会;
关键词:
NANOPOROUS THIN-FILMS;
BLOCK-COPOLYMERS;
ARRAYS;
LITHOGRAPHY;
ARRANGEMENT;
MICELLES;
POLYMERS;
GRAPHOEPITAXY;
NANOCRYSTALS;
DEVICES;
D O I:
10.1039/c2cc36756d
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Well-defined ferrocene-containing triblock copolymers were synthesized by atom transfer radical polymerization and self-assembled into highly ordered hexagonal arrays of cylinders via solvent annealing. The thin films were further used as a template and converted into highly ordered iron oxide nanoparticles (alpha-Fe2O3) by UV/ozonolysis and thermal pyrolysis.
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页码:4373 / 4375
页数:3
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