Optical properties of KDP crystals doped with pyrenetetrasulfonic acid salt

被引：8
作者：
Pritula, I. M. [1 ]
Bezkrovnaya, O. N. [1 ]
Lopin, A. V. [1 ]
Kolybaeva, M. I. [1 ]
Puzikov, V. M. [1 ]
Zubatyuk, R. I. [1 ]
Shishkin, O. V. [1 ]
Gayvoronsky, V. Ya. [2 ]
机构：
[1] Natl Acad Sci Ukraine, SSI Inst Single Crystals, Inst Single Crystals, UA-61001 Kharkov, Ukraine
[2] Natl Acad Sci Ukraine, Inst Phys, UA-03680 Kiev, Ukraine
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2013年 / 74卷 / 03期
关键词：
Inorganic compounds; Crystal growth; Luminescence; GROWTH; FLUORESCENCE; PYRENE;
D O I：
10.1016/j.jpcs.2012.11.009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
KDP crystals with incorporated molecules of the luminophore 1,3,6,8-pyrenetetrasulfonic acid tetrasodium salt (SPA) were grown from KH2PO4 solutions by the temperature lowering method. The luminescence spectra of KDP/SPA crystals and SPA solutions in distilled water and in KH2PO4 solutions, were studied. The increase of the dye content gives rise to excimer luminescence in the solutions and in KDP crystals, which is due to the formation of associated dye molecules. SPA molecules possessing negative electrostatic potential are incorporated into the pyramidal growth sector of KDP crystal. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：452 / 456
页数：5
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