Thiourea-phosphonium salts from amino acids: cooperative phase-transfer catalysts in the enantioselective aza-Henry reaction

被引：108

作者：

Cao, Dongdong ^{[1
]}

Chai, Zhuo ^{[2
]}

Zhang, Jiaxing ^{[2
]}

Ye, Zhengqing ^{[2
]}

Xiao, Hua ^{[1
]}

Wang, Hongyu ^{[1
]}

Chen, Jinhao ^{[2
]}

Wu, Xiaoyu ^{[1
]}

Zhao, Gang ^{[1
,2
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 53期

基金：

中国国家自然科学基金;

关键词：

NITRO-MANNICH REACTION; HYDROGEN-BONDING SITE; BETA-KETO-ESTERS; AMMONIUM-SALTS; ASYMMETRIC HYDROPHOSPHONYLATION; TRANSFER ALKYLATION; DUAL FUNCTIONS; BRONSTED ACID; AMINATION; ORGANOCATALYSTS;

D O I：

10.1039/c3cc42864h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New chiral bifunctional thiourea-phosphonium salts have been developed based on natural amino acids as highly efficient phase-transfer catalysts in the enantioselective aza-Henry reaction.

引用

页码：5972 / 5974

页数：3

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