Solid acids as catalysts for the conversion of D-xylose, xylan and lignocellulosics into furfural in ionic liquid

被引：66

作者：

Zhang, Luxin ^{[1
]}

Yu, Hongbing ^{[1
]}

Wang, Pan ^{[2
]}

机构：

[1] Nankai Univ, Coll Environm Sci & Engn, Tianjin 300071, Peoples R China

[2] Beijing Technol & Business Univ, Sch Food & Chem Engn, Beijing 102488, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2013年 / 136卷

关键词：

Furfural; Solid acids; Ionic liquid; Lignocellulosic biomass; BIOMASS; DEHYDRATION; STRAW; WATER;

D O I：

10.1016/j.biortech.2013.03.054

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

With the aim to develop an ecologically viable catalytic pathway for furfural production without the use of inorganic acids, H3PW12O40, Amberlyst-5 and NKC-9 (macroporous styrene-based sulfonic acid resin) were used as catalysts for producing furfural from xylose, xylan and lignocellulosic biomass in [BMIM]Cl under microwave irradiation at atmospheric pressure. A surprisingly high furfural yield of 93.7% from xylan was obtained by H3PW12O40 at 160 C in 10 min. The degradation of furfural affected by single addition of [BMIM]Cl and solid acids was also investigated. The IL could be easily recycled and reused with stable solvent capacity for multiple runs (5x) after the product furfural was extracted with ethyl acetate. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：515 / 521

页数：7

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