Sonochemical synthesis of a novel nanorod diaqua(pyridine-2,6-dicarboxylato)copper(II) 3-D supramolecular network: new precursor to prepare pure phase nanosized copper(II) oxide

被引：13

作者：

Gupta, Rimpy ^{[1
]}

Sanotra, Sumit ^{[1
]}

Sheikh, Haq Nawaz ^{[1
]}

Kalsotra, Bansi Lal ^{[1
]}

Gupta, Vivek Kumar ^{[2
]}

Rajnikant ^{[2
]}

机构：

[1] Univ Jammu, Dept Chem, Jammu 180006, India

[2] Univ Jammu, Dept Phys, Jammu 180006, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 22期

关键词：

Sonochemical; Supramolecular; BET surface area; Nanoparticles; COORDINATION POLYMER; DIFFERENT MORPHOLOGIES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; FRAMEWORKS; COMPLEX; SOLIDS;

D O I：

10.1080/00958972.2012.728592

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nanosized copper(II) supramolecular compound, [Cu(dipic)(H2O)(2)](n) (1) [dipic = 2, 6-pyridinedicarboxylate], has been synthesized by sonochemical method and characterized by elemental analysis, scanning electron microscopy, X-ray powder diffraction, IR spectroscopy, TGA/DTA, and BET surface area studies. The structure of single crystalline 1 developed from nanosized 1 has been determined by X-ray crystallography and further characterized by scanning electron microscopy, TGA/DTA, and BET surface area studies. The XRD studies reveal that nanorod copper(II) supramolecular compound adopts a 3-D supramolecular network owing to extensive hydrogen-bonding and pi-pi stacking. Solvent effects on size and morphology of nanosized 1 have been studied. Calcination of nanosized 1 at 500 degrees C under air yields CuO nanoparticles.

引用

页码：3917 / 3931

页数：15

共 43 条

[1] Sonochemical syntheses and characterization of nano-structured three-dimensional lead(II) coordination polymer constructed of fumaric acid [J].