Mg deposition observed by in situ electrochemical Mg K-edge X-ray absorption spectroscopy

被引：58
作者：
Arthur, Timothy S. [1 ]
Glans, Per-Anders [2 ]
Matsui, Masaki [1 ]
Zhang, Ruigang [1 ]
Ma, Biwu [3 ]
Guo, Jinghua [2 ]
机构：
[1] Toyota Res Inst N Amer, Ann Arbor, MI 48105 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2012年 / 24卷
关键词：
In situ electrochemical/XAS; Magnesium batteries; Interface analysis; Electrodeposition; ELECTROLYTE-SOLUTIONS; MAGNESIUM DEPOSITION; STRUCTURAL-ANALYSIS; BATTERIES;
D O I：
10.1016/j.elecom.2012.08.018
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical deposition of magnesium from [Mg-2(mu-Cl)(3)center dot 6(OC4H8)](+) has been monitored in situ with X-ray absorption spectroscopy. The viability of the cell design was confirmed by a reversible shift in the X-ray absorption near-edge spectroscopy (XANES) of the Mg K-edge. In situ electrochemical XANES revealed the presence of an interfacial Mg intermediate below the equilibrium Mg/Mg2+ potential. A new method has been established to directly observe the complex electrochemical reduction process from Mg electrolytes. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 46
页数：4
相关论文
共 50 条
[1]   Simulated sulfur K-edge X-ray absorption spectroscopy database of lithium thiophosphate solid electrolytes [J].
Guo, Haoyue ;
Carbone, Matthew R. ;
Cao, Chuntian ;
Qu, Jianzhou ;
Du, Yonghua ;
Bak, Seong-Min ;
Weiland, Conan ;
Wang, Feng ;
Yoo, Shinjae ;
Artrith, Nongnuch ;
Urban, Alexander ;
Lu, Deyu .
SCIENTIFIC DATA, 2023, 10 (01)
[2]   Fe K-Edge X-ray absorption Near-Edge spectroscopy and morphology analyses of LiFePO4 powders [J].
Nihlatunnur, N. ;
Latif, C. ;
Negara, V. S., I ;
Wongtepa, W. ;
Pratapa, S. .
MATERIALS TODAY-PROCEEDINGS, 2021, 44 :3361-3364
[3]   X-ray Absorption Spectroscopy and X-ray Diffraction Studies of the Thermal and Li-Driven Electrochemical Dehydrogenation of Nanocrystalline Complex Hydrides Mg2MHx (M = Co, Ni) [J].
Provost, K. ;
Zhang, J. ;
Zaidi, W. ;
Paul-Boncour, V. ;
Bonnet, J. -P. ;
Cuevas, F. ;
Belin, S. ;
Aymard, L. ;
Latroche, M. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (51) :29554-29567
[4]   Electrochemical discharge of nanocrystalline magnetite: structure analysis using X-ray diffraction and X-ray absorption spectroscopy [J].
Menard, Melissa C. ;
Takeuchi, Kenneth J. ;
Marschilok, Amy C. ;
Takeuchi, Esther S. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (42) :18539-18548
[5]   Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy [J].
Wan, Liwen F. ;
Wright, Joshua ;
Perdue, Brian R. ;
Fister, Timothy T. ;
Kim, Soojeong ;
Apblett, Christopher A. ;
Prendergast, David .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (26) :17326-17329
[6]   The Electro-Deposition/Dissolution of CuSO4 Aqueous Electrolyte Investigated by In Situ Soft X-ray Absorption Spectroscopy [J].
Velasco-Velez, Juan-Jesus ;
Skorupska, Katarzyna ;
Frei, Elias ;
Huang, Yu-Cheng ;
Dong, Chung-Li ;
Su, Bing-Jian ;
Hsu, Cheng-Jhih ;
Chou, Hung-Yu ;
Chen, Jin-Ming ;
Strasser, Peter ;
Schloegl, Robert ;
Knop-Gericke, Axel ;
Chuang, Cheng-Hao .
JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (02) :780-787
[7]   In Situ Synchrotron X-Ray Absorption Spectroscopy Studies of Anode Materials for Rechargeable Batteries [J].
Wu, Zhibin ;
Kong Pang, Wei ;
Chen, Libao ;
Johannessen, Bernt ;
Guo, Zaiping .
BATTERIES & SUPERCAPS, 2021, 4 (10) :1547-1566
[8]   Effect of Mg doping on the local structure of LiMgyCo1-yO2 cathode material investigated by X-ray absorption spectroscopy [J].
Cheng, J. H. ;
Pan, C. J. ;
Nithya, C. ;
Thirunakaran, R. ;
Gopukumar, S. ;
Chen, C. H. ;
Lee, J. F. ;
Chen, J. M. ;
Sivashanmugam, A. ;
Hwang, B. J. .
JOURNAL OF POWER SOURCES, 2014, 252 :292-297
[9]   Electrosynthesis of ZnO nanorods and nanotowers: Morphology and X-ray Absorption Near Edge Spectroscopy studies [J].
Sigircik, Gokmen ;
Erken, Ozge ;
Tuken, Tunc ;
Gumus, Cebrail ;
Ozkendir, Osman M. ;
Ufuktepe, Yuksel .
APPLIED SURFACE SCIENCE, 2015, 340 :1-8
[10]   Formation of an SEI on a LiMn2O4 cathode during room temperature charge-discharge cycling studied by soft X-ray absorption spectroscopy at the Fluorine K-edge [J].
Chung, Kyung Yoon ;
Yoon, Won-Sub ;
Kim, Kwang-Bum ;
Cho, Byung-Won ;
Yang, Xiao-Qing .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2011, 41 (11) :1295-1299
12345