Benzene reduction by alkylation in a solid phosphoric acid catalyzed olefin oligomerization process

被引：16
作者：
Sakuneka, Tebogo M. [1 ]
Nel, Reinier J. J. [1 ]
de Klerk, Arno [1 ]
机构：
[1] Sasol Technol Res & Dev, Fischer Tropsch Refinery Catalysis, ZA-1947 Sasolburg, South Africa
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2008年 / 47卷 / 19期
关键词：
D O I：
10.1021/ie800672p
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A refinery with a solid phosphoric acid olefin oligomerization unit can reduce the benzene content of its motor-gasoline by co-feeding the benzene-containing material to that unit. It has been shown that benzene co-feeding has little disruptive impact on olefin oligomerization, and > 80% benzene conversion to alkylated benzenes has been demonstrated during a commercial test run on an industrial unit. Benzene conversion is insensitive to reactor inlet temperature in the range of 160-180 degrees C and remains better than 80% at liquid hourly space velocities of up to 1.5 h(-1). A high propene content in the olefinic feed promotes benzene alkylation, and although butene-rich feeds can be employed, benzene conversion is lower.
引用
收藏
页码：7178 / 7183
页数：6
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