From Containers to Catalysts: Supramolecular Catalysis within Cucurbiturils

被引：160
作者：
Pemberton, Barry C. [1 ]
Raghunathan, Ramya [1 ]
Volla, Sabine [1 ]
Sivaguru, Jayaraman [1 ]
机构：
[1] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58108 USA
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 39期
基金：
美国国家科学基金会;
关键词：
catalysis by confinement; cucurbiturils; molecular recognition; photocatalysis; supramolecular catalysis; BIOMIMETIC CHEMISTRY; PHOTODIMERIZATION; CYCLODEXTRIN; DERIVATIVES; HOST; REACTIVITY; WATER; COMPLEXATION; RECOGNITION; SELECTIVITY;
D O I：
10.1002/chem.201202083
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cucurbiturils are a family of molecular container compounds with superior molecular recognition properties. The use of cucurbiturils for supramolecular catalysis is highlighted in this concept. Both photochemical reactions as well as thermal transformations are reviewed with an eye towards tailoring substrates for supramolecular catalysis mediated by cucurbiturils.
引用
收藏
页码：12178 / 12190
页数：13
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