SO2 gas sensor based on Al3+ and O2- ion conducting solids with La2O2SO4 auxiliary electrode

被引:6
|
作者
Hasegawa, I
Hasegawa, Y
Imanaka, N
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Handai Frontier Res Ctr, Suita, Osaka 5650871, Japan
关键词
sulfur dioxide; sensor; solid electrolyte; solid state chemistry; rare earth oxysulfate;
D O I
10.1166/sl.2005.009
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new solid electrolyte type sulfur dioxide (SO2) gas sensor was fabricated by the combination of trivalent aluminum cation conducting (Al0.2Zr0.8)(20/19)Nb(PO4)(3) and divalent oxide anion conducting yttria stabilized zirconia (YSZ) with Li2SO4-doped La2O2SO4 as the sensing auxiliary electrode. The present sensor shows such a practical performance of a rapid, stable, continuous, and reproducible response at 500 degrees C, and the linear relationship which obeys the Nernst relationship was clearly observed between the sensor EMF output and the logarithm of the SO2 gas concentration.
引用
收藏
页码:27 / 30
页数:4
相关论文
共 50 条
  • [1] Sulfur dioxide gas sensor based on Al3+ and O2- ion conducting solids with gadolinium oxysulfate based auxiliary sensing electrode
    Inaba, Yuichi
    Nagai, Tsukasa
    Tamura, Shinji
    Imanaka, Nobuhito
    SENSOR LETTERS, 2008, 6 (03) : 458 - 461
  • [2] SO2 concentration cell with Li2O-B2O3-Li2SO4 solid electrolyte
    Kasahara, A
    Nakamura, H
    Ogawa, Y
    Isida, Y
    Matuda, K
    JOURNAL OF THE JAPAN INSTITUTE OF METALS, 1996, 60 (10) : 957 - 961
  • [3] SO2 concentration cell with Li2O-B2O3-Li2SO4 solid electrolyte
    Nakamura, H
    Ogawa, Y
    Kasahara, A
    Isida, Y
    Matsuda, K
    MATERIALS TRANSACTIONS JIM, 1998, 39 (02): : 281 - 285
  • [4] Sulfur dioxide gas sensor based on Zr4+ and O2- ion conducting solid electrolytes with lanthanum oxysulfate as an auxiliary sensing electrode
    Uneme, Yasuhisa
    Tamura, Shinji
    Imanaka, Nobuhito
    SENSORS AND ACTUATORS B-CHEMICAL, 2013, 177 : 529 - 534
  • [5] SO2 gas sensor based on Ag-Ag2SO4-BaSO4 sensing electrode
    Wangyan Shi
    Tao Feng
    Dangyu Jiang
    Qiang Li
    Ionics, 2015, 21 : 1719 - 1723
  • [6] SO2 gas sensor based on Ag-Ag2SO4-BaSO4 sensing electrode
    Shi, Wangyan
    Feng, Tao
    Jiang, Dangyu
    Li, Qiang
    IONICS, 2015, 21 (06) : 1719 - 1723
  • [7] A chlorine gas sensor based on the combination of Mg2+ cation conducting and O2- anion conducting solid electrolytes with lanthanum oxychloride as an auxiliary electrode
    Imanaka, N
    Okamoto, K
    Adachi, G
    ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (02) : 49 - 51
  • [8] A new SO2 gas sensor based on an Mg2+ conducting solid electrolyte
    Wang, L
    Kumar, RV
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 543 (02): : 109 - 114
  • [9] Potentiometric SO2 gas sensor based on a thick film of Ca2+ ion conducting solid electrolyte
    L. Wang
    R.V. Kumar
    Journal of Applied Electrochemistry, 2006, 36 : 173 - 178
  • [10] Potentiometric SO2 gas sensor based on a thick film of Ca2+ ion conducting solid electrolyte
    Wang, L
    Kumar, RV
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2006, 36 (02) : 173 - 178