Efficient light hydrocarbon separation and CO2 capture and conversion in a stable MOF with oxalamide-decorated polar tubes

被引：133

作者：

Li, Xiu-Yuan ^{[1
]}

Li, Yong-Zhi ^{[1
]}

Yang, Yun ^{[1
]}

Hou, Lei ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Zhu, Zhonghua ^{[2
]}

机构：

[1] Northwest Univ, Key Lab Synthet & Nat Funct Mol Chem, Shaanxi Key Lab Physicoinorgan Chem, Minist Educ,Coll Chem & Mat Sci, Xian 710069, Shaanxi, Peoples R China

[2] Univ Queensland, Sch Chem Engn, Brisbane, Qld 4072, Australia

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 96期

基金：

澳大利亚研究理事会;

关键词：

METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; SELECTIVE SORPTION; GAS-ADSORPTION; CATALYST; METHANE; SITES; COCATALYST; TOPOLOGY; EXCHANGE;

D O I：

10.1039/c7cc08298c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first strontium-based MOF possessing polar tubular channels embedded with a high density of open Lewis acidic metal sites and basic oxalamide groups was constructed, which shows not only a high CO2 and C2H6 adsorption capability and significant selectivity for CO2 over both CH4 and CO, and for C2H6 over CH4, but also size-selective chemical conversion of CO2 with epoxides producing cyclic carbonates under ambient conditions.

引用

页码：12970 / 12973

页数：4

共 36 条

[1] Analysis of High and Selective Uptake of CO2 in an Oxamide-Containing {Cu2(OOCR)4}-Based Metal-Organic Framework [J].

Alsmail, Nada H. ;

Suyetin, Mikhail ;

Yan, Yong ;

Cabot, Rafel ;

Krap, Cristina P. ;

Lu, Jian ;

Easun, Timothy L. ;

Bichoutskaia, Elena ;

Lewis, William ;

Blake, Alexander J. ;

Schroeder, Martin .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (24) :7317-7324

[2] Alkaline Earth Metal (Mg, Sr, Ba)-Organic Frameworks Based on 2,2′,6,6′-Tetracarboxybiphenyl for Proton Conduction [J].

Dong, Xi-Yan ;

Hu, Xiao-Peng ;

Yao, Hong-Chang ;

Zang, Shuang-Quan ;

Hou, Hong-Wei ;

Mak, Thomas C. W. .

INORGANIC CHEMISTRY, 2014, 53 (22) :12050-12057

[3] Carbon Dioxide Adsorption in Amine-Functionalized Mixed-Ligand Metal-Organic Frameworks of UiO-66 Topology [J].

Ethiraj, Jayashree ;

Albanese, Elisa ;

Civalleri, Bartolomeo ;

Vitillo, Jenny G. ;

Bonino, Francesca ;

Chavan, Sachin ;

Shearer, Greig C. ;

Lillerud, Karl Petter ;

Bordiga, Silvia .

CHEMSUSCHEM, 2014, 7 (12) :3382-3388

[4] Construction of Ultrastable Porphyrin Zr Metal-Organic Frameworks through Linker Elimination [J].

Feng, Dawei ;

Chung, Wan-Chun ;

Wei, Zhangwen ;

Gu, Zhi-Yuan ;

Jiang, Hai-Long ;

Chen, Ying-Pin ;

Darensbourg, Donald J. ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (45) :17105-17110

[5] A Rigid Nested Metal-Organic Framework Featuring a Thermoresponsive Gating Effect Dominated by Counterions [J].

Gao, Qiang ;

Xu, Jian ;

Cao, Dapeng ;

Chang, Ze ;

Bu, Xian-He .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (48) :15027-15030

[6] Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO2 under Ambient Conditions [J].

Gao, Wen-Yang ;

Chen, Yao ;

Niu, Youhong ;

Williams, Kia ;

Cash, Lindsay ;

Perez, Pastor J. ;

Wojtas, Lukasz ;

Cai, Jianfeng ;

Chen, Yu-Sheng ;

Ma, Shengqian .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (10) :2615-2619

[7] Well-Defined Silica-Supported Calcium Reagents: Control of Schlenk Equilibrium by Grafting [J].

Gauvin, Regis M. ;

Buch, Frank ;

Delevoye, Laurent ;

Harder, Sjoerd .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (17) :4382-4393

[8] Water-Stable In(III)-Based Metal-Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4 [J].

Guo, Zhen-Ji ;

Yu, Jiamei ;

Zhang, Yong-Zheng ;

Zhang, Jian ;

Chen, Ya ;

Wu, Yufeng ;

Xie, Lin-Hua ;

Li, Jian-Rong .

INORGANIC CHEMISTRY, 2017, 56 (04) :2188-2197

[9]

HALASA AF, 2006, Patent No. 7087549

[10] A robust doubly interpenetrated metal-organic framework constructed from a novel aromatic tricarboxylate for highly selective separation of small hydrocarbons [J].

He, Yabing ;

Zhang, Zhangjing ;

Xiang, Shengchang ;

Fronczek, Frank R. ;

Krishna, Rajamani ;

Chen, Banglin .

CHEMICAL COMMUNICATIONS, 2012, 48 (52) :6493-6495

← 1 2 3 4 →