From solutions to surfaces: A novel molecular imprinting method based on the conformational changes of boronic-acid-appended poly(L-lysine)

被引：0

作者：

Friggeri, A

Kobayashi, H

Shinkai, S

Reinhoudt, DN

机构：

[1] Japan Sci & Technol Corp, Chemotransfigurat Project, Fukuoka 8390861, Japan

[2] Univ Twente, Chemotransfigurat Project, MESA Res Inst, NL-7500 AE Enschede, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 24期

关键词：

molecular recognition; carbohydrates; surface chemistry;

D O I：

10.1002/1521-3773(20011217)40:24<4729::AID-ANIE4729>3.0.CO;2-M

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dominant solution-phase conformation of a polymer can be fixed to a surface (see scheme). Boronic acid appended poly(L-lysine) assumes different conformations in the presence of D-glucose or D-fructose. When the polymer-glucose complex is anchored to a gold surface, an imprinted interface with "molecular memory" for glucose over fructose can be prepared.

引用

页码：4729 / +

页数：4

共 29 条

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