Benzocarborano[2,1-b:3,4-b′]dithiophene Containing Conjugated Polymers: Synthesis, Characterization, and Optoelectronic Properties

被引：17
|
作者：
Marshall, Jonathan [1 ,2 ]
Schroeder, Bob C. [1 ,2 ]
Bronstein, Hugo [3 ]
Meager, Iain [1 ,2 ]
Rossbauer, Stephan [2 ,4 ]
Yaacobi-Gross, Nir [2 ,4 ]
Buchaca-Domingo, Ester [2 ,5 ]
Anthopoulos, Thomas D. [2 ,4 ]
Stingelin, Natalie [2 ,5 ]
Beavis, Peter [6 ]
Heeney, Martin [1 ,2 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ London Imperial Coll Sci Technol & Med, Ctr Plast Elect, London SW7 2AZ, England
[3] UCL, Dept Chem, London WC1H 0AJ, England
[4] Univ London Imperial Coll Sci Technol & Med, Dept Phys, London SW7 2AZ, England
[5] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England
[6] AWE, Reading RG7 4PR, Berks, England
来源：
MACROMOLECULES | 2014年 / 47卷 / 01期
关键词：
HIGH-PERFORMANCE AMBIPOLAR; O-CARBORANE; BENZOCARBORANE; TRANSISTORS; COPOLYMERS; BNCT; HOLE;
D O I：
10.1021/ma402273w
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the stannylation of a benzocarborano[2,1-b:3,4-b']dithiophene monomer and its polymerization by Stille polycondensation with solubilized cyclopentadithiophene and diketopyrrolopyrrole derivatives. The physical, material, and optoelectronic properties of the resultant conjugated copolymers are reported, demonstrating that benzocarboranodithiophene acts as a mildly electron-withdrawing monomer.
引用
收藏
页码：89 / 96
页数：8
相关论文
共 50 条
  • [41] Rational Optimization of Benzo[2,1-b;3,4-b′]dithilophene-Containing Polymers for Organic Field-Effect Transistors
    Rieger, Ralph
    Beckmann, Dirk
    Pisula, Wojciech
    Steffen, Werner
    Kastler, Marcel
    Muellen, Klaus
    ADVANCED MATERIALS, 2010, 22 (01) : 83 - +
  • [42] An electrochromic polymer based on cyclopenta[2,1-b;3,4-b′]dithiophene: Effect of a single atom alteration on the electrochemical and optical properties of the polymer backbone
    Tutuncu, Esra
    Varlik, Bengisu
    Kesimal, Busra
    Cihaner, Atilla
    Ozkut, Merve Icli
    SYNTHETIC METALS, 2020, 265
  • [43] Effect of hexadecyl groups in 4 position on the electrochemical polymerisation of 4H-cyclopenta[2,1-b:3,4-b′]dithiophene
    Casalbore-Miceli, G
    Camaioni, N
    Geri, A
    Cristani, M
    Fichera, AM
    Berlin, A
    SYNTHETIC METALS, 2000, 108 (01) : 47 - 56
  • [44] Synthesis and characterization of poly(3,5-didodecyl-cyclopenta[2,1-b;3,4-b′]dithiophen-4-one)
    Zhang, Cheng
    Sun, Jianyuan
    Sun, Sam-Shajing
    SYNTHETIC METALS, 2016, 221 : 275 - 283
  • [45] Synthesis and Properties of Alternating Copolymers Based on 4H-Cyclopenta[2,1-b:3,4-b']dithiophene and 4H-Dithieno[3,2-b:2',3'-d]silol
    Drozdov, F., V
    Surin, N. M.
    Peregudova, S. M.
    Trukhanov, V. A.
    Dmitryakov, P., V
    Chvalun, S. N.
    Parashchuk, D. Yu
    Ponomarenko, S. A.
    POLYMER SCIENCE SERIES B, 2019, 61 (01) : 56 - 76
  • [46] Synthesis and Properties of Alternating Copolymers Based on 4H-Cyclopenta[2,1-b:3,4-b']dithiophene and 4H-Dithieno[3,2-b:2',3'-d]silol
    F. V. Drozdov
    N. M. Surin
    S. M. Peregudova
    V. A. Trukhanov
    P. V. Dmitryakov
    S. N. Chvalun
    D. Yu. Parashchuk
    S. A. Ponomarenko
    Polymer Science, Series B, 2019, 61 : 56 - 76
  • [47] Synthesis of a quinoidal dithieno[2,3-d;2′,3′-d]benzo[2,1-b;3,4-b′]-dithiophene based open-shell singlet biradicaloid
    Xia, Debin
    Keerthi, Ashok
    An, Cunbin
    Baumgarten, Martin
    ORGANIC CHEMISTRY FRONTIERS, 2017, 4 (01): : 18 - 21
  • [48] Dye-sensitized solar cells based on organic dyes with naphtho[2,1-b:3,4-b′]dithiophene as the conjugated linker (vol 1, pg 13328, 2013)
    Wang, Xiaoxu
    Guo, Lei
    Xia, Ping Fang
    Zheng, Fan
    Wong, Man Shing
    Zhu, Zhengtao
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) : 18147 - 18147
  • [49] 4,4′-spirobi[cyclopenta[2,1-b;3,4-b′]dithiophene]:: A new generation of heterocyclic spiro-type molecule
    Londenberg, Joscha
    Saragi, Tobat R. L.
    Suske, Irina
    Salbeck, Josef
    ADVANCED MATERIALS, 2007, 19 (22) : 4049 - +
  • [50] Photovoltaic performance of narrow bandgap copolymer derivatives based on 4H-Cyclopenta[2,1-b;3,4-b′]dithiophene units
    Vanderzande, Dirk J. M.
    Van Mierloo, Sarah
    Marin, Lidia
    Maes, Wouter
    Lutsen, Laurence
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
12345