Discovery of C60O3 isomer having C3v symmetry

被引：60

作者：

Tajima, Y ^{[1
]}

Takeuchi, K ^{[1
]}

机构：

[1] RIKEN, Nanomat Proc Lab, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 05期

关键词：

D O I：

10.1021/jo010908n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A hitherto undetected type of C60O3 isomer was found in the reaction solution of C-60 with m-chloroperoxybenzoic acid by means of a chromatographic technique using two different columns. Both electronic spectroscopy and atmospheric pressure chemical ionization (APCI) mass-spectroscopy examinations show its C3nu symmetry, in which three oxygen atoms are added onto one benzenoid ring of C-60.

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页码：1696 / 1698

页数：3

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