Photoacoustic spectroscopy of Ln3+ (Nd, Ho, and Er) doped ThO2

被引：10
|
作者：
Chandrasekhar, D. [1 ]
Gupta, Santosh K. [2 ]
Godbole, Sv. [2 ]
机构：
[1] Bhabha Atom Res Ctr, Product Dev Div, Mumbai 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Radiochem, Mumbai 400085, Maharashtra, India
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1051卷
关键词：
ThO2; Lanthanides; PAS; Non-radiative; Covalency; LUMINESCENCE; EU3+; SITE;
D O I：
10.1016/j.molstruc.2013.08.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Undoped and ThO2:Ln(3+) (Ln = Nd, Ho, and Er) were synthesized by wet chemical route and characterized using X-ray diffraction (XRD). PAS was used to investigate electronic absorption of Nd3+, Ho3+ and Er3+ in thorium dioxide as well as of pure rare earth oxide powder Ln(2)O(3) (Ln = Nd, Ho, and Er). PA spectra were also obtained for aqueous solution of lanthanides for evaluating various covalency parameters. Various covalency parameters like nephelauxetic ratio (beta), covalency factor (b(1/2)) and Sinha parameter (delta) were evaluated for pure oxide powder and for rare earth doped thoria for all these system from their individual PA spectra. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：95 / 100
页数：6
相关论文
共 50 条
  • [1] Microstructure investigation and multicolor upconversion in Yb3+/Ln3+ (Ln = Er/Tm/Ho) ions doped α-Sialon
    Jeong, Sang Hoon
    Kshetri, Yuwaraj K.
    Kim, Seung Ho
    Cho, Sung Hun
    Lee, Soo W.
    PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2019, 29 (05) : 549 - 555
  • [2] Multicolor-tunable emissions of YOF: Ln3+ /Yb3+ (Ln3+ = Ho3+, Er3+, Tm3+) nanophosphors
    Perisa, Jovana
    Papan, Jelena
    Dolic, Slobodan D.
    Jovanovic, Dragana J.
    Drarnianin, Miroslav D.
    DYES AND PIGMENTS, 2018, 155 : 233 - 240
  • [3] Luminescence properties of Y2O3:Bi3+, Ln3+ (Ln=Sm, Eu, Dy, Er, Ho) and the sensitization of Ln3+ by Bi3+
    Ju, Guifang
    Hu, Yihua
    Chen, Li
    Wang, Xiaojuan
    Mu, Zhongfei
    Wu, Haoyi
    Kang, Fengwen
    JOURNAL OF LUMINESCENCE, 2012, 132 (08) : 1853 - 1859
  • [4] Synthesis and luminescence properties of Ln3+ (Ln3+ = Er3+, Sm3+)-doped barium lanthanum tungstate BaLa2WO7 phosphors
    Yan, Shao-An
    Wang, Jian-Wen
    Chang, Yee-Shin
    Hwang, Weng-Sing
    Chang, Yen-Hwei
    OPTICAL MATERIALS, 2011, 34 (01) : 147 - 151
  • [5] Controlled electron and hole trapping in YPO4:Ce3+,Ln3+ and LuPO4:Ce3+,Ln3+ (Ln=Sm, Dy, Ho, Er, Tm)
    Krumpel, Andreas H.
    Bos, Adrie J. J.
    Bessiere, Aurelie
    van der Kolk, Erik
    Dorenbos, Pieter
    PHYSICAL REVIEW B, 2009, 80 (08)
  • [6] Preparation and up-conversion luminescence of β-SiAlON:Ln3+ (Ln=Yb/Ho, Yb/Er) microparticles
    Yang, Zhigang
    Zhao, Zhengyan
    Liu, Bitao
    Wang, Yuhua
    MATERIALS LETTERS, 2013, 93 : 32 - 35
  • [7] Fabrication, microstructure and upconversion luminescence of Yb3+/Ln3+ (Ln=Ho, Er, Tm) co-doped Y2Ti2O7 ceramics
    Guo, Yanyan
    Wang, Dianyuan
    Zhao, Xin
    Wang, Fang
    MATERIALS RESEARCH BULLETIN, 2016, 73 : 84 - 89
  • [8] Multicolor upconversion luminescence of GdVO4:Ln3+/Yb3+ (Ln3+ = Ho3+, Er3+, Tm3+, Ho3+/Er3+/Tm3+) nanorods
    Gavrilovic, Tamara V.
    Jovanovic, Dragana J.
    Smits, Krisjanis
    Dramicanin, Miroslav D.
    DYES AND PIGMENTS, 2016, 126 : 1 - 7
  • [9] A novel and tunable upconversion luminescent material GdPO4:Yb3+, Ln3+ (Ln = Er, Tm, Ho)
    Fu, Zuoling
    Sheng, Tianqi
    Wu, Zhijian
    Yu, Yingning
    Cui, Tian
    MATERIALS RESEARCH BULLETIN, 2014, 56 : 138 - 142
  • [10] Solvothermal synthesis and upconversion properties in Yb3+/Ln3+ (Ln3+=Er3+/Ho3+/Tm3+) codoped In2O3 nanoparticles with fine stability
    Shi, Yuchao
    Li, Jing
    Cui, Wenhao
    Peng, Yaru
    Huang, Yuxin
    Chen, Li
    OPTICAL MATERIALS, 2021, 121
12345