Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes

被引：29
作者：
Dong, Yi [1 ,2 ]
Liu, Gang [1 ,2 ,3 ,4 ]
机构：
[1] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
[2] Peking Union Med Coll, Beijing 100050, Peoples R China
[3] Tsinghua Univ, Tsinghua Peking Ctr Life Sci, Beijing 100084, Peoples R China
[4] Tsinghua Univ, Sch Med, Dept Pharmacol & Pharmaceut Sci, Beijing 100084, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 73期
基金：
中国国家自然科学基金;
关键词：
ORTHO-ALKENYLATION; BOND ACTIVATION; FUNCTIONALIZATION; VERSATILE; ALKENES; SELECTIVITY; INHIBITORS; REACTIVITY; SULTONES; SILANOL;
D O I：
10.1039/c3cc44690e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Rh-catalyzed ortho C-H olefination of arenes directed by a sulfonic acid group was developed with good yields and a broad reaction scope. Efficient performance of the catalyst caused this electron-poor aromatic C-H to be activated effectively and unactivated alkenes are also suitable for this reaction.
引用
收藏
页码：8066 / 8068
页数：3
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