Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes

被引：28

作者：

Dong, Yi ^{[1
,2
]}

Liu, Gang ^{[1
,2
,3
,4
]}

机构：

[1] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China

[2] Peking Union Med Coll, Beijing 100050, Peoples R China

[3] Tsinghua Univ, Tsinghua Peking Ctr Life Sci, Beijing 100084, Peoples R China

[4] Tsinghua Univ, Sch Med, Dept Pharmacol & Pharmaceut Sci, Beijing 100084, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 73期

基金：

中国国家自然科学基金;

关键词：

ORTHO-ALKENYLATION; BOND ACTIVATION; FUNCTIONALIZATION; VERSATILE; ALKENES; SELECTIVITY; INHIBITORS; REACTIVITY; SULTONES; SILANOL;

D O I：

10.1039/c3cc44690e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Rh-catalyzed ortho C-H olefination of arenes directed by a sulfonic acid group was developed with good yields and a broad reaction scope. Efficient performance of the catalyst caused this electron-poor aromatic C-H to be activated effectively and unactivated alkenes are also suitable for this reaction.

引用

页码：8066 / 8068

页数：3

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