Anion-directed assembly of a non-interpenetrated square-grid metal-organic framework with nanoscale porosity

被引：43

作者：

Mitra, Atanu

Hubley, Christian T.

Panda, Dillip K.

Clark, Ronald J.

Saha, Sourav ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 59期

关键词：

ELECTRON-TRANSFER; RATIONAL DESIGN; PI INTERACTIONS; CARBON-DIOXIDE; COORDINATION; SEPARATION; CATENATION;

D O I：

10.1039/c3cc43178a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A non-interpenetrated square grid metal-organic framework (MOF) comprised of octahedral Zn(II) ions and linear N,N'-di (4-pyridyl)-1,4,5,8-naphthalenediimide (DPNDI) ligands was formed in the presence of noncoordinating perchlorate counterions that occupied the cavities of the porous network by forming CH center dot center dot center dot anion hydrogen bonds with DPNDI ligands, whereas a linear coordination polymer was obtained when Zn(II)-coordinated nitrate ions were present as counterions.

引用

页码：6629 / 6631

页数：3

共 45 条

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