Anion-directed assembly of a non-interpenetrated square-grid metal-organic framework with nanoscale porosity

被引：43
|
作者：
Mitra, Atanu
Hubley, Christian T.
Panda, Dillip K.
Clark, Ronald J.
Saha, Sourav [1 ]
机构：
[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 59期
关键词：
ELECTRON-TRANSFER; RATIONAL DESIGN; PI INTERACTIONS; CARBON-DIOXIDE; COORDINATION; SEPARATION; CATENATION;
D O I：
10.1039/c3cc43178a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A non-interpenetrated square grid metal-organic framework (MOF) comprised of octahedral Zn(II) ions and linear N,N'-di (4-pyridyl)-1,4,5,8-naphthalenediimide (DPNDI) ligands was formed in the presence of noncoordinating perchlorate counterions that occupied the cavities of the porous network by forming CH center dot center dot center dot anion hydrogen bonds with DPNDI ligands, whereas a linear coordination polymer was obtained when Zn(II)-coordinated nitrate ions were present as counterions.
引用
收藏
页码：6629 / 6631
页数：3
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