Sol-gel method for preparing a novel red-emitting phosphor YVO4:Sm3+, Eu3+ with ideal red color emission

被引：13

作者：

Xia, Siyu ^{[1
]}

Guan, Anxiang ^{[1
]}

Chen, Peican ^{[1
]}

Wang, Guofang ^{[1
]}

Geng, Yue ^{[1
]}

Zhou, Liya ^{[1
]}

机构：

[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China

来源：

SUPERLATTICES AND MICROSTRUCTURES | 2016年 / 97卷

基金：

中国国家自然科学基金;

关键词：

Photoluminescence; Phosphor; Sol-gel method; Standard red color; ENERGY-TRANSFER; LUMINESCENT PROPERTIES; ENHANCED LUMINESCENCE; OPTICAL-PROPERTIES; LN; PHOTOLUMINESCENCE; NANOPARTICLES; DY3+; CE3+; TB3+;

D O I：

10.1016/j.spmi.2016.06.039

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A series of novel color-tunable phosphors YVO4:Sm3+, Eu3+ was synthesized using a sol-gel method. The crystal structure and photoluminescence properties of the synthesized phosphors were measured and analyzed. By changing the ratio of Sm3+-Eu3+, the color of these phosphors can be changed from orange to red. This phenomenon was closely related to the energy transfer from Sm3+ to Eu3+, and analysis demonstrated that the energy-transfer mechanism arose from quadrupole-quadrupole interaction, with a critical distance of about 10.28 angstrom. The Commission International deL'Eclairage value of YVO4:0.05Sm(3+), 0.11Eu(3+) enabled the achievement of the standard red coordinates (0.67, 0.33). All these results indicated that the red phosphors can be used as a red component of white-light-emitting diodes. (C) 2016 Published by Elsevier Ltd.

引用

页码：319 / 326

页数：8

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