Application of photo catalysis for mitigation of carbon dioxide

被引：27
作者：
Jeyalakshmi, V. [1 ,2 ]
Rajalakshmi, K. [1 ]
Mahalakshmy, R. [2 ]
Krishnamurthy, K. R. [1 ]
Viswanathan, B. [1 ]
机构：
[1] Indian Inst Technol, Natl Ctr Catalysis Res, Madras 600036, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Thiagarajar Coll, Dept Chem, Madurai 625021, Tamil Nadu, India
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2013年 / 39卷 / 06期
关键词：
Photo catalysis; photo catalytic reduction; CO2; mitigation; Structure-photophysical properties-performance relationships; PHOTOCATALYTIC H-2 EVOLUTION; CO2; REDUCTION; TIO2; POWDERS; HETEROGENEOUS PHOTOCATALYSIS; ELECTRONIC-STRUCTURE; AQUEOUS SUSPENSIONS; SOLAR-ENERGY; WATER; PHOTOREDUCTION; TITANIA;
D O I：
10.1007/s11164-012-0783-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photo catalytic reduction of carbon dioxide by water or artificial photosynthesis to yield hydrocarbons (methane and methanol, etc., termed "solar fuels") is being studied extensively, with the twin objectives of developing an effective means of limiting atmospheric CO2 levels and evolving a sustainable alternative route for production of fuels and chemicals. This short review covers the origin and thermodynamic and kinetic features of the process, the basic photocatalytic principles involved, the rationale behind the choice of different catalysts and their performance, the effect of process conditions, the effect of the structural and photophysical properties of the different catalysts on their performance, mechanistic pathways, surface transformations, challenges involved in the practical application of the process, and future directions for research.
引用
收藏
页码：2565 / 2602
页数：38
相关论文
共 133 条
  • [1] PHOTOCATALYTIC REDUCTION OF CARBON-DIOXIDE TO HYDROCARBON USING COPPER-LOADED TITANIUM-DIOXIDE
    ADACHI, K
    OHTA, K
    MIZUNO, T
    [J]. SOLAR ENERGY, 1994, 53 (02) : 187 - 190
  • [2] Photocatalytic conversion of carbon dioxide into methanol using zinc-copper-M(III) (M = aluminum, gallium) layered double hydroxides
    Ahmed, Naveed
    Shibata, Yoshiyuki
    Taniguchi, Tatsuo
    Izumi, Yasuo
    [J]. JOURNAL OF CATALYSIS, 2011, 279 (01) : 123 - 135
  • [3] The advancements in sol-gel method of doped-TiO2 photocatalysts
    Akpan, U. G.
    Hameed, B. H.
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 375 (01) : 1 - 11
  • [4] PHOTOCATALYTIC REDUCTION OF CO-2 ON ANCHORED TITANIUM-OXIDE CATALYSTS
    ANPO, M
    CHIBA, K
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3): : 207 - 212
  • [5] The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation
    Anpo, M
    Takeuchi, M
    [J]. JOURNAL OF CATALYSIS, 2003, 216 (1-2) : 505 - 516
  • [6] PHOTOCATALYTIC REDUCTION OF CO2 WITH H2O ON VARIOUS TITANIUM-OXIDE CATALYSTS
    ANPO, M
    YAMASHITA, H
    ICHIHASHI, Y
    EHARA, S
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 396 (1-2): : 21 - 26
  • [7] Photocatalytic reduction of CO2 with H2O on titanium oxides anchored within micropores of zeolites: Effects of the structure of the active sites and the addition of Pt
    Anpo, M
    Yamashita, H
    Ichihashi, Y
    Fujii, Y
    Honda, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14): : 2632 - 2636
  • [8] Photocatalytic reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 mesoporous zeolite catalysts
    Anpo, M
    Yamashita, H
    Ikeue, K
    Fujii, Y
    Zhang, SG
    Ichihashi, Y
    Park, DR
    Suzuki, Y
    Koyano, K
    Tatsumi, T
    [J]. CATALYSIS TODAY, 1998, 44 (1-4) : 327 - 332
  • [9] Visible-light photocatalysis in nitrogen-doped titanium oxides
    Asahi, R
    Morikawa, T
    Ohwaki, T
    Aoki, K
    Taga, Y
    [J]. SCIENCE, 2001, 293 (5528) : 269 - 271
  • [10] Photocatalytic behaviour of metal-loaded TiO2 aqueous dispersions and films
    Bellardita, M.
    Addamo, M.
    Di Paola, A.
    Palmisano, L.
    [J]. CHEMICAL PHYSICS, 2007, 339 (1-3) : 94 - 103
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