Palladium(II)-Catalyzed ortho-Olefination of Benzylic Phosphonic Monoesters

被引：64

作者：

Meng, Xiangjian ^{[1
]}

Kim, Sunggak ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 08期

关键词：

C-H ACTIVATION; CATALYZED DIRECT OLEFINATION; ORTHO-BROMINATION; ORTHO-LITHIATION; DIRECTING GROUP; BOND FORMATION; PALLADIUM; LIGAND; ALKENYLATION; ARYLATION;

D O I：

10.1021/ol400565r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new monophosphonic acid directing group is successfully utilized in the Pd(II)-catalyzed ortho-olefination of benzylic phosphonic monoesters and offers further development of other phosphoryl-related directing groups in the transition-metal-catalyzed C-H activations.

引用

页码：1910 / 1913

页数：4

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