Chromatography-Free and Eco-Friendly Synthesis of Aryl Tosylates and Mesylates

被引：42

作者：

Lei, Xiangyang ^{[1
]}

Jalla, Anusha ^{[1
]}

Abou Shama, Mhd A. ^{[1
]}

Stafford, Jamie M. ^{[1
]}

Cao, Billy ^{[1
]}

机构：

[1] Lamar Univ, Dept Chem & Biochem, Beaumont, TX 77710 USA

来源：

SYNTHESIS-STUTTGART | 2015年 / 47卷 / 17期

关键词：

aryl tosylates; aryl mesylates; tosylation; mesylation; green chemistry; CROSS-COUPLING REACTIONS; SOLVENT-FREE; NICKEL PRECATALYST; PALLADIUM; ALCOHOLS; PHENOLS; MILD; SULFONYLATION; DERIVATIVES; CHLORIDES;

D O I：

10.1055/s-0034-1378867

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two chromatography-free and eco-friendly protocols have been developed to synthesize aryl tosylates and mesylates by the tosylation and mesylation of the corresponding hydroxyarenes, respectively. These protocols are superior to other known ones regarding the simplicity, reaction time and conditions, the range of substrates, yields, and environmental friendliness.

引用

页码：2578 / 2585

页数：8

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