Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]•2H2O}∞

被引：36
作者：
Galán-Mascarós, JR
Clemente-Juan, JM
Dunbar, KR [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Univ Valencia, Inst Ciencias Mol, Burjassot 46100, Spain
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 13期
关键词：
D O I：
10.1039/B109585b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}(n-)(n) was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.
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页码：2710 / 2713
页数：4
相关论文
共 94 条
[51]  
Jetti R. K. R., 1999, CRYST ENG, V2, P215
[52]   Voltammetric study of the transfer of heavy metal ions at the nitrobenzene | water interface assisted by 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine [J].
Katano, H ;
Kuboyama, H ;
Senda, M .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 483 (1-2) :117-123
[53]   Hard magnets based on transition metal complexes with the dicyanamide anion, {N(CN)2}- [J].
Kurmoo, M ;
Kepert, CJ .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) :1515-1524
[54]  
Kusukawa T, 2001, ANGEW CHEM INT EDIT, V40, P1879
[55]  
LaDuca RL, 2000, INORG CHEM COMMUN, V3, P248
[56]   CHEMISTRY OF IRON WITH DIPICOLINIC ACID .3. HEPTACOORDINATED IRON IN [(DIPICH)(2)FE-II(OH2)] AND [(DIPIC)(2)FE-2(II)(OH2)(6)]CENTER-DOT-2DIPICH(2) [J].
LAINE, P ;
GOURDON, A ;
LAUNAY, JP ;
TUCHAGUES, JP .
INORGANIC CHEMISTRY, 1995, 34 (21) :5150-5155
[57]  
LANDEE CP, 1991, NATO ADV SCI I E-APP, V198, P395
[58]   Ferromagnetic ordering, anisotropy, and spin reorientation for the cyano-bridged bimetallic compound Mn2(H2O)5Mo(CN)7•4H2O (α phase) [J].
Larionova, J ;
Clérac, R ;
Sanchiz, J ;
Kahn, O ;
Golhen, S ;
Ouahab, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) :13088-13095
[59]   Two-dimensional coordination polymers with one-dimensional magnetic chains:: Hydrothermal synthesis, crystal structure, and magnetic and thermal properties of ∞2[MCl2(4,4′-bipyridine)] (M = Fe, Co, Ni, Co/Ni) [J].
Lawandy, MA ;
Huang, XY ;
Wang, RJ ;
Li, J ;
Lu, JY ;
Yuen, T ;
Lin, CL .
INORGANIC CHEMISTRY, 1999, 38 (23) :5410-5414
[60]   Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].
Leininger, S ;
Olenyuk, B ;
Stang, PJ .
CHEMICAL REVIEWS, 2000, 100 (03) :853-907
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