Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]•2H2O}∞

被引：35

作者：

Galán-Mascarós, JR

Clemente-Juan, JM

Dunbar, KR ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Univ Valencia, Inst Ciencias Mol, Burjassot 46100, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 13期

关键词：

D O I：

10.1039/B109585b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}(n-)(n) was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.

引用

页码：2710 / 2713

页数：4

共 94 条

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