Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]•2H2O}∞

被引：35
作者：
Galán-Mascarós, JR
Clemente-Juan, JM
Dunbar, KR [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Univ Valencia, Inst Ciencias Mol, Burjassot 46100, Spain
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 13期
关键词：
D O I：
10.1039/B109585b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}(n-)(n) was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.
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页码：2710 / 2713
页数：4
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