Structure and function revealed with submolecular resolution at the liquid-solid interface

被引：57
作者：
Elemans, Johannes A. A. W.
De Feyter, Steven [1 ]
机构：
[1] Katholieke Univ Leuven, Dept Chem, Div Mol & Nanomat, B-3001 Louvain, Belgium
来源：
SOFT MATTER | 2009年 / 5卷 / 04期
关键词：
SCANNING-TUNNELING-MICROSCOPY; ASSEMBLED SUPRAMOLECULAR RECTANGLE; 2-DIMENSIONAL MOLECULAR NETWORK; SOLVENT-INDUCED POLYMORPHISM; SELECTIVE GUEST INCLUSION; AU(111) SURFACES; SELF-ORGANIZATION; TRIMESIC ACID; GRAPHITE SURFACE; NEAT LIQUID;
D O I：
10.1039/b811090e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The liquid-solid interface is a unique medium to support the self-assembly of molecules into surface-confined networks. Non-covalent interactions are key in forming these two-dimensional (2D) architectures, and a deep understanding is crucial for successful 2D crystal engineering. Scanning tunnelling microscopy is the tool of choice to reveal the structure and function of these patterns with subnanometre resolution. A recent success is the formation of 2D nanoporous molecular patterns and their host guest chemistry. However, this is not the only functionality addressed by this review. Surface-confined molecular architectures at the liquid solid interface are also relevant in the field of molecular electronics. Furthermore, inducing and probing chemical reactivity at the single-molecule level at the liquid solid interface might turn out to be one of the most exciting developments.
引用
收藏
页码：721 / 735
页数：15
相关论文
共 50 条
[41]   Liquid-Solid Transfer Process of Ordered Structures in Efficient Polymer Photovoltaic Materials [J].
Ren, Jiaxuan ;
Wang, Li-Ming ;
Li, Qingduan ;
Guo, Lingzhi ;
Liao, Xiaolan ;
Xie, Zhenhua ;
Zhang, Jiabin ;
Zhang, Kai ;
Cao, Zhixiong ;
Cai, Yue-Peng ;
Liu, Shengjian ;
Huang, Fei .
ACS APPLIED POLYMER MATERIALS, 2023, 6 (01) :986-996
[42]   Bilayer Molecular Assembly at a Solid/Liquid Interface as Triggered by a Mild Electric Field [J].
Zheng, Qing-Na ;
Liu, Xuan-He ;
Liu, Xing-Rui ;
Chen, Ting ;
Yan, Hui-Juan ;
Zhong, Yu-Wu ;
Wang, Dong ;
Wan, Li-Jun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (49) :13395-13399
[43]   Self-assembled 2D patterns of structural isomers in isobutenyl compounds revealed by STM at solid/liquid interface [J].
Kikkawa, Yoshihiro ;
Tsuzuki, Seiji ;
Kashiwada, Ayumi ;
Hiratani, Kazuhisa .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 537 :580-590
[44]   Molecular Patterning at a Liquid/Solid Interface: The Foldamer Approach [J].
Li, Min ;
Gobbo, Cristian ;
De Cat, Inge ;
Eelkema, Rienk ;
Vanaverbeke, Bernard ;
Lazzaroni, Roberto ;
De Feyter, Steven ;
van Escht, Jan .
LANGMUIR, 2011, 27 (22) :13598-13605
[45]   Tunnel barrier height oscillations at the solid/liquid interface [J].
Hugelmann, M ;
Schindler, W .
SURFACE SCIENCE, 2003, 541 (1-3) :L643-L648
[46]   Nanoelectrical analysis of single molecules and atomic-scale materials at the solid/liquid interface [J].
Nirmalraj, Peter ;
Thompson, Damien ;
Molina-Ontoria, Agustin ;
Sousa, Marilyne ;
Martin, Nazario ;
Gotsmann, Bernd ;
Riel, Heike .
NATURE MATERIALS, 2014, 13 (10) :947-953
[47]   Controlling the Position of Functional Groups at the Liquid/Solid Interface: Impact of Molecular Symmetry and Chirality [J].
De Cat, Inge ;
Gobbo, Cristian ;
Van Averbeke, Bernard ;
Lazzaroni, Roberto ;
De Feyter, Steven ;
van Esch, Jan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (51) :20942-20950
[48]   From One-Dimensional Disordered Racemate to Ordered Racemic Conglomerates through Metal-Coordination-Driven Self-Assembly at the Liquid-Solid Interface [J].
Hu, Tianze ;
Minoia, Andrea ;
Velpula, Gangamallaiah ;
Ryskulova, Kanykei ;
Van Hecke, Kristof ;
Lazzaroni, Roberto ;
Mali, Kunal S. ;
Hoogenboom, Richard ;
De Feyter, Steven .
CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (02)
[49]   Chemistry at the square nanometer: reactivity at liquid/solid interfaces revealed with an STM [J].
Munninghoff, Joris A. W. ;
Elemans, Johannes A. A. W. .
CHEMICAL COMMUNICATIONS, 2017, 53 (11) :1769-1788
[50]   STM Investigation of the Y[C6S-Pc]2 and Y[C4O-Pc]2 Complex at the Solution-Solid Interface: Substrate Effects, Submolecular Resolution, and Vacancies [J].
Rana, Shammi ;
Jiang, Jianzhuang ;
Korpany, Katalin, V ;
Mazur, Ursula ;
Hipps, K. W. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2021, 125 (02) :1421-1431
12345