Self-assembly of organic luminophores with gelation-enhanced emission characteristics

被引:179
作者
Zhao, Zujin [1 ]
Lam, Jacky W. Y. [2 ,3 ]
Tang, Ben Zhong [2 ,3 ,4 ]
机构
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Zhejiang, Peoples R China
[2] Hong Kong Univ Sci & Technol, State Key Lab Mol Neurosci, Inst Mol Funct Mat, Dept Chem, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Inst Adv Study, Kowloon, Hong Kong, Peoples R China
[4] S China Univ Technol, State Key Lab Luminescent Mat & Devices, SCUT HKUST Joint Res Lab, Guangdong Innovat Res Team, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
AGGREGATION-INDUCED EMISSION; EXCITATION-ENERGY TRANSFER; LIGHT-EMITTING-DIODES; FLUORESCENCE EMISSION; SUPRAMOLECULAR GELS; SOFT MATERIALS; TUNABLE EMISSION; ORGANOGEL SYSTEM; PI-ORGANOGELS; NANOPARTICLES;
D O I
10.1039/c3sm27969c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fluorescent self-assembled organogels are interesting supramolecular soft materials with polymer-like structures and have received particular attention due to their fascinating properties and promising practical applications. However, most planar pi-conjugated gelators are highly emissive in the solution state but become weak emitters when self-assembled. Recently, a novel phenomenon of aggregation-induced emission (AIE) has drawn increasing research interest and has been the subject of numerous investigations. This intriguing finding paves a new way for creating fluorescent organogels by utilizing gelators with AIE characteristics. This review focuses on the recent advances in fluorescent organogels with gelation-enhanced emission features. Various kinds of low molecular weight gelators consisting of typical AIE luminogens, conventional planar chromophores, and photoactive molecules are introduced and the mechanisms for the emission enhancement are discussed.
引用
收藏
页码:4564 / 4579
页数:16
相关论文
共 98 条
[91]   Aggregation-induced emission, self-assembly, and electroluminescence of 4,4′-bis(1,2,2-triphenylvinyl)biphenyl [J].
Zhao, Zujin ;
Chen, Shuming ;
Shen, Xiaoyuan ;
Mahtab, Faisal ;
Yu, Yong ;
Lu, Ping ;
Lam, Jacky W. Y. ;
Kwok, Hoi Sing ;
Tang, Ben Zhong .
CHEMICAL COMMUNICATIONS, 2010, 46 (05) :686-688
[92]   Tetraphenylethene: a versatile AIE building block for the construction of efficient luminescent materials for organic light-emitting diodes [J].
Zhao, Zujin ;
Lam, Jacky W. Y. ;
Tang, Ben Zhong .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (45) :23726-23740
[93]   Using tetraphenylethene and carbazole to create efficient luminophores with aggregation-induced emission, high thermal stability, and good hole-transporting property [J].
Zhao, Zujin ;
Chan, Carrie Y. K. ;
Chen, Shuming ;
Deng, Chunmei ;
Lam, Jacky W. Y. ;
Jim, Cathy K. W. ;
Hong, Yuning ;
Lu, Ping ;
Chang, Zhengfeng ;
Chen, Xiaopeng ;
Lu, Ping ;
Kwok, Hoi Sing ;
Qiu, Huayu ;
Tang, Ben Zhong .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (10) :4527-4534
[94]   Stereoselective Synthesis, Efficient Light Emission, and High Bipolar Charge Mobility of Chiasmatic Luminogens [J].
Zhao, Zujin ;
Lam, Jacky W. Y. ;
Chan, Carrie Y. K. ;
Chen, Shuming ;
Liu, Jianzhao ;
Lu, Ping ;
Rodriguez, Mario ;
Maldonado, Jose-Luis ;
Ramos-Ortiz, Gabriel ;
Sung, Herman H. Y. ;
Williams, Ian D. ;
Su, Huimin ;
Wong, Kam Sing ;
Ma, Yuguang ;
Kwok, Hoi Sing ;
Qiu, Huayu ;
Tang, Ben Zhong .
ADVANCED MATERIALS, 2011, 23 (45) :5430-+
[95]   Synthesis, Structure, Aggregation-Induced Emission, Self-Assembly, and Electron Mobility of 2,5-Bis(triphenylsilylethynyl)-3,4-diphenylsiloles [J].
Zhao, Zujin ;
Liu, Dandan ;
Mahtab, Faisal ;
Xin, Linyuan ;
Shen, Zhongfang ;
Yu, Yong ;
Chan, Carrie Y. K. ;
Lu, Ping ;
Lam, Jacky W. Y. ;
Sung, Herman H. Y. ;
Williams, Ian D. ;
Yang, Bing ;
Ma, Yuguang ;
Tang, Ben Zhong .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (21) :5998-6008
[96]   Molecular anchors in the solid state: Restriction of intramolecular rotation boosts emission efficiency of luminogen aggregates to unity [J].
Zhao, Zujin ;
Lu, Ping ;
Lam, Jacky W. Y. ;
Wang, Zhiming ;
Chan, Carrie Y. K. ;
Sung, Herman H. Y. ;
Williams, Ian D. ;
Ma, Yuguang ;
Tang, Ben Zhong .
CHEMICAL SCIENCE, 2011, 2 (04) :672-675
[97]   Aggregation-Induced Emission of Tetraarylethene Luminogens [J].
Zhao, Zujin ;
Lam, Jacky W. Y. ;
Tang, Ben Zhong .
CURRENT ORGANIC CHEMISTRY, 2010, 14 (18) :2109-2132
[98]   Structural Modulation of Solid-State Emission of 2,5-Bis(trialkylsilylethynyl)-3,4-diphenylsiloles [J].
Zhao, Zujin ;
Wang, Zhiming ;
Lu, Ping ;
Chan, Carrie Y. K. ;
Liu, Dandan ;
Lam, Jacky W. Y. ;
Sung, Herman H. Y. ;
Williams, Ian D. ;
Ma, Yuguang ;
Tang, Ben Zhong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) :7608-7611